(E)-tetradec-7-ene epoxide

Base Information

• Chemical Name: (E)-tetradec-7-ene epoxide
• CAS No.: 70973-36-3
• Molecular Formula: C₁₄H₂₈O
• Molecular Weight: 212.376
• Mol file: 70973-36-3.mol

Synonyms:

Chemical Property of (E)-tetradec-7-ene epoxide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (E)-tetradec-7-ene epoxide

There total 8 articles about (E)-tetradec-7-ene epoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

(E)-7-tetradecene (41446-63-3) → (E)-tetradec-7-ene epoxide (70973-36-3,81171-85-9,85721-27-3)

Guidance literature:

With ethylenediaminetetraacetic acid; 1,1,1-trifluoro-2-propanone; dihydrogen peroxide; potassium carbonate; In acetonitrile; at 0 - 20 ℃; for 5h; pH=11.0;

DOI:10.1021/jo001180y

Reference yield:

2-[(1R,2R)-2-(tert-Butyl-dimethyl-silanyloxy)-1-hexyl-octylsulfanyl]-benzothiazole → (E)-tetradec-7-ene epoxide (70973-36-3,81171-85-9,85721-27-3)

Guidance literature:

Multi-step reaction with 3 steps

1: 80 percent / m-chloroperbenzoic acid / CH₂Cl₂

2: Bu₄NF / tetrahydrofuran / 18 h / 0 to 18 deg C

3: 87 percent / m-chloroperbenzoic acid, NaHCO₃ / CH₂Cl₂ / 18 h / Ambient temperature

With tetrabutyl ammonium fluoride; sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; dichloromethane;

Reference yield:

2-[(7R,8R)-8-(tert-Butyl-dimethyl-silanyloxy)-tetradecane-7-sulfonyl]-benzothiazole → (E)-tetradec-7-ene epoxide (70973-36-3,81171-85-9,85721-27-3)

Guidance literature:

Multi-step reaction with 2 steps

1: Bu₄NF / tetrahydrofuran / 18 h / 0 to 18 deg C

2: 87 percent / m-chloroperbenzoic acid, NaHCO₃ / CH₂Cl₂ / 18 h / Ambient temperature

With tetrabutyl ammonium fluoride; sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; dichloromethane;

upstream raw materials:

(E)-7-tetradecene

(Z)-7-tetradecene

(Z)-7-tetradecene oxide

Downstream raw materials:

tetradec-8-en-7-ol

(7R,8S)-8-Phenyltellanyl-tetradecan-7-ol

Refernces

• 1、 Shu,Shi. "An efficient ketone-catalyzed epoxidation using hydrogen peroxide as oxidant". . p. 8807 - 8810. Retrieved 2007/10/03.
• 2、 Muzart, Jacques,Riahi, Abdelkhalek. "Palladium- and light-enhanced ring-opening of oxiranes by copper chloride". . p. 323 - 336. Retrieved 2007/10/02.