2-(Benzyloxy)-1-broMonaphthalene

Base Information

• Chemical Name: 2-(Benzyloxy)-1-broMonaphthalene
• CAS No.: 41908-23-0
• Molecular Formula: C17H13BrO
• Molecular Weight: 313.194
• Hs Code.: 2909309090
• Mol file: 41908-23-0.mol

Synonyms:p-methoxyphenyl bromide;Of BroMoanisole;1-Bromo-2-naphthol benzyl ether;p-anisylbromide;p-bromoanisol;Anisyl bromide;4-methoxyphenyl bromide;1-bromo-4-methoxybenzylnaphthalene;1-bromo-4-methoxy-benzene;4-BROMO ANISOL;4-methoxy bromobenzene;4-methoxy-1-bromobenzene;p-Bromanisole;P-BROMOANISOLE;2-benzyloxy-1-bromonaphthalene;benzyl 1-bromo-2-naphthyl ether;

Chemical Property of 2-(Benzyloxy)-1-broMonaphthalene

Chemical Property:

• Melting Point: 104-106 °C(Solv: dichloromethane (75-09-2); ligroine (8032-32-4))
• Boiling Point: 430.1±20.0 °C(Predicted)
• PSA: 9.23000
• Density: 1.395±0.06 g/cm3(Predicted)
• LogP: 5.18130
• Storage Temp.: 2-8°C

Purity/Quality:

99% ^*data from raw suppliers

2-(Benzyloxy)-1-bromonaphthalene ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-(Benzyloxy)-1-broMonaphthalene

There total 10 articles about 2-(Benzyloxy)-1-broMonaphthalene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

1-bromo-2-naphthol (573-97-7) + benzyl bromide (100-39-0) → 1-bromo-2-(phenylmethoxy)naphthalene (41908-23-0)

Guidance literature:

With potassium carbonate; In N,N-dimethyl-formamide; at 70 ℃; for 12h; Inert atmosphere;

DOI:10.1021/ol101336y

Reference yield: 81.0%

1-bromo-2-naphthol (573-97-7) → 1-bromo-2-(phenylmethoxy)naphthalene (41908-23-0)

Guidance literature:

With potassium carbonate; sodium iodide; In acetone; for 5h; Heating;

DOI:10.1021/ol0258029

Reference yield: 80.0%

1-bromo-2-naphthol (573-97-7) + benzyl chloride (100-44-7) → 1-bromo-2-(phenylmethoxy)naphthalene (41908-23-0)

Guidance literature:

With potassium carbonate; In acetonitrile; Heating;

DOI:10.1021/jo060271d

upstream raw materials:

2-benzyloxynaphthalene

1-bromo-2-naphthol

benzyl bromide

benzyl chloride

Downstream raw materials:

1-methyl-2-phenylnaphtho[2,1-b]furan

(2-naphthyl)phenylmethanol

2,2'-bis(benzyloxy)-1,1'-binaphthalene

(R)-1,1'-Bi-2-naphthol

Refernces

• 1、 Budén, María E.,Heredia, Micaela D.,Puiatti, Marcelo,Rossi, Roberto A.. "Visible light mediated synthesis of 6H-benzo[c]chromenes: transition-metal-free intramolecular direct C-H arylation". supporting information. p. 228 - 239. Retrieved 2021/12/29.
• 2、 Kumar, Prashant,Shirke, Rajendra P.,Yadav, Sonu,Ramasastry. "Catalytic Enantioselective Synthesis of Axially Chiral Diarylmethylidene Indanones". . p. 4909 - 4914. Retrieved 2021/06/30.