Lithium, (tributylstannyl)-

Base Information

• Chemical Name: Lithium, (tributylstannyl)-
• CAS No.: 4226-01-1
• Molecular Formula: C12H27LiSn
• Molecular Weight: 296.997
• Mol file: 4226-01-1.mol

Synonyms:

Chemical Property of Lithium, (tributylstannyl)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Refernces

THE REACTION OF TRIBUTYLSTANNYLLITHIUM WITH 2-ETHOXY-3-ALKENENITRILES. A NEW METHOD FOR THE PREPARATION OF γ-ETHOXYALLYLSTANNANES AND DIENOL ETHERS

10.1246/cl.1986.345

The research presents a novel method for the preparation of γ-ethoxyallylstannanes and dienol ethers. The key reaction involves the use of tributylstannyllithium with 2-ethoxy-3-alkenenitriles, yielding γ-ethoxyallylstannanes in good to high yields through an SN2' reaction mechanism. The study also explores the synthesis of dienol ethers by reacting trimethylsiloxy alkenenitriles, which are derived from 2-ethoxy-3-alkenenitriles, with tributylstannyllithium. The chemicals that played crucial roles in this research include tributylstannyllithium as the reducing agent, 2-ethoxy-3-alkenenitriles as the starting materials, lithium diisopropylamide (LDA) for deprotonation, various aldehydes for alkylation, and chlorotrimethylsilane for silylation. The innovative aspect of this work lies in the efficient and selective synthesis of these compounds, which have significant applications in organic synthesis.