THE REACTION OF TRIBUTYLSTANNYLLITHIUM WITH 2-ETHOXY-3-ALKENENITRILES. A NEW METHOD FOR THE PREPARATION OF γ-ETHOXYALLYLSTANNANES AND DIENOL ETHERS

DOI: 10.1246/cl.1986.345

Source and publish data:

Chemistry Letters p. 345 - 348 (1986)

Update date:2022-09-26

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Authors:

Takeda, Takeshi

Ando, Kazuo

Ohshima, Hiroyuki

Inoue, Masami

Fujiwara, Tooru

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Article abstract of DOI:10.1246/cl.1986.345

The reaction of 2-ethoxy-3-alkenenitriles with tributylstannyllithium gave the S_N2' product, γ-ethoxyallylstannanes (3), in good yields.When 3 have a trimethylsiloxyl group at δ-position, the corresponding substituted 2-ethoxy-1,3-butadienes we

Full text of DOI:10.1246/cl.1986.345

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