1,3,5-Tris[4-(bromomethyl)phenyl]benzene

Base Information

• Chemical Name: 1,3,5-Tris[4-(bromomethyl)phenyl]benzene
• CAS No.: 42837-44-5
• Molecular Formula: C27H21Br3
• Molecular Weight: 585.176
• DSSTox Substance ID: DTXSID60494683
• Nikkaji Number: J982.956C
• Mol file: 42837-44-5.mol

Synonyms:42837-44-5;1,3,5-tris[4-(bromomethyl)phenyl]benzene;4,4''-Bis(bromomethyl)-5'-(4-(bromomethyl)phenyl)-1,1':3',1''-terphenyl;1,1':3',1''-Terphenyl, 4,4''-bis(bromomethyl)-5'-[4-(bromomethyl)phenyl]-;YSZC345;SCHEMBL10049247;DTXSID60494683;AKOS025296164;1,3,5-tris(4-bromomethylphenyl)benzene

Chemical Property of 1,3,5-Tris[4-(bromomethyl)phenyl]benzene

Chemical Property:

• XLogP3: 8.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 6
• Exact Mass: 583.91729
• Heavy Atom Count: 30
• Complexity: 401

Purity/Quality:

97% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC(=CC=C1CBr)C2=CC(=CC(=C2)C3=CC=C(C=C3)CBr)C4=CC=C(C=C4)CBr

Technology Process of 1,3,5-Tris[4-(bromomethyl)phenyl]benzene

There total 8 articles about 1,3,5-Tris[4-(bromomethyl)phenyl]benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

1,3,5-tris[(4-hydroxymethyl)phenyl]benzene (353289-47-1) → 1,3,5-tris(4-bromomethylphenyl)benzene (42837-44-5)

Guidance literature:

With hydrogen bromide; for 5h; Heating;

DOI:10.1039/b101425k

Reference yield: 89.0%

1,3,5-tris(4-methyl-phenyl)-benzene (50446-43-0) → 1,3,5-tris(4-bromomethylphenyl)benzene (42837-44-5)

Guidance literature:

With N-Bromosuccinimide; dibenzoyl peroxide; at 90 ℃;

DOI:10.1016/j.poly.2019.03.014

Reference yield:

para-methylacetophenone (122-00-9) → 1,3,5-tris(4-bromomethylphenyl)benzene (42837-44-5)

Guidance literature:

Multi-step reaction with 2 steps

1: 84 percent / SiCl₄; ethanol / 24 h / 20 °C

2: 58 percent / N-bromosuccinimide; BPO / benzene / 3 h / Heating

With N-Bromosuccinimide; tetrachlorosilane; ethanol; dibenzoyl peroxide; In benzene;

DOI:10.1016/j.tetlet.2007.06.052

upstream raw materials:

1,3,5-tris(4-methyl-phenyl)-benzene

1,3,5-tris[(4-hydroxymethyl)phenyl]benzene

para-methylacetophenone

1,3,5-tris(4-formylphenyl)benzene

Downstream raw materials:

1,3,5-tris<4-(benzylamino)methyl)phenyl>benzene

1,3,5-tris<4-(<<4-cyanoethylthio-3',4'-bis(methylthio)-tetrathiafulvalen-3-yl>thio>methyl)phenyl>benzene

1,3,5-tris<4-(<<3'(4')-cyanoethylthio-4,4'(3')-bis(methylthio)-tetrathiafulvalen-3-yl>thio>methyl)phenyl>benzene