Cyclohexanamine, N-(1-methylpropyl)-

Base Information

• Chemical Name: Cyclohexanamine, N-(1-methylpropyl)-
• CAS No.: 42966-62-1
• Molecular Formula: C10H21N
• Molecular Weight: 155.283
• Mol file: 42966-62-1.mol

Synonyms:

Chemical Property of Cyclohexanamine, N-(1-methylpropyl)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Cyclohexanamine, N-(1-methylpropyl)-

There total 8 articles about Cyclohexanamine, N-(1-methylpropyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

cyclohexylamine (108-91-8,157973-60-9) + iso-butanol (78-92-2,15892-23-6) → 2-(N-cyclohexyl)iminobutane (42966-62-1)

Guidance literature:

With [Zr₆O₄(OH)4]⁽¹²⁺⁾*5.7C₈H₅NO₄^(2-)*0.3C₁₃H₂₀N₂O*0.3Ir⁽¹⁺⁾; hydrogen; at 80 ℃; for 24h; under 4500.45 Torr; Autoclave; Green chemistry;

DOI:10.1002/cctc.201402101

Reference yield: 65.0%

cyclohexylamine (108-91-8,157973-60-9) + butanone (78-93-3) → 2-(N-cyclohexyl)iminobutane (42966-62-1)

Guidance literature:

With N,N,N'N'-tetramethyl-1,3-propanediamine; carbon monoxide; water; hexarhodium hexadecacarbonyl; In 2-ethoxy-ethanol; at 80 ℃; for 5h; under 6080 Torr;

DOI:10.1246/bcsj.64.602

Reference yield:

nitrobenzene (98-95-3,26969-40-4) + iso-butanol (78-92-2,15892-23-6) → 2-(N-cyclohexyl)iminobutane (42966-62-1) + cyclohexylamine (108-91-8,157973-60-9)

Guidance literature:

With hydrogen; In water; at 150 ℃; for 10h; under 22502.3 Torr; chemoselective reaction; Molecular sieve; Autoclave;

DOI:10.1016/j.apcata.2020.117536

upstream raw materials:

3-cyclohexylamino-1-butyne

N-cyclohexylbutylidene-2-imine

cyclohexylamine

butanone

Downstream raw materials:

5-(N-cyclohexyl-N-s-butyl)aminomethylene-2,2-dimethyl-1,3-dioxane-4,6-dione

sec-Butyl-(2-chloro-ethyl)-cyclohexyl-amine

2-(sec-Butyl-cyclohexyl-amino)-ethanol

N-Isopropoxycarbonyl-3-(N-sec.-butyl-cyclohexylcarbamoyloxy)anilin

Refernces

• 1、 Rasero-Almansa,Corma,Iglesias,Sanchez. "Design of a bifunctional Ir-Zr based metal-organic framework heterogeneous catalyst for the N-alkylation of amines with alcohols". . p. 1794 - 1800. Retrieved 2014/06/24.