3-Buten-2-one, 3-(trimethylsilyl)-

Base Information

Chemical Name:3-Buten-2-one, 3-(trimethylsilyl)-
CAS No.:43209-86-5
Molecular Formula:C7H14OSi
Molecular Weight:142.273
Hs Code.:2931900090
DSSTox Substance ID:DTXSID00451159
Nikkaji Number:J713.336G
Wikidata:Q82271039
Mol file:43209-86-5.mol

Synonyms:43209-86-5;3-(Trimethylsilyl)-3-buten-2-one;3-Buten-2-one, 3-(trimethylsilyl)-;3-trimethylsilylbut-3-en-2-one;SCHEMBL5551390;DTXSID00451159;SDWXIGKTVZPGPG-UHFFFAOYSA-N;methyl 1-trimethylsilylvinyl ketone;1-(trimethylsilyl)-vinyl methyl ketone;3-TRIMETHYLSILYL-3-BUTEN-2-ONE;3-(TRIMETHYLSILYL)BUT-3-EN-2-ONE;FT-0737735;EN300-7170326

Suppliers and Price of 3-Buten-2-one, 3-(trimethylsilyl)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
3-TRIMETHYLSILYL-3-BUTEN-2-ONE 95.00%
5MG
$ 503.06

Total 8 raw suppliers

Chemical Property of 3-Buten-2-one, 3-(trimethylsilyl)-

Chemical Property:

PSA：17.07000
LogP:2.00900
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:2
Exact Mass:142.081391600
Heavy Atom Count:9
Complexity:142

Purity/Quality:

98%Min ^*data from raw suppliers

3-TRIMETHYLSILYL-3-BUTEN-2-ONE 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(=O)C(=C)[Si](C)(C)C
Physical properties bp 72 °C/50 mmHg.
Uses 3-Trimethylsilyl-3-buten-2-one is a methyl vinyl ketone homolog useful as a Michael acceptor in annulation reactions, γ,δ-unsaturated ketone formation, Diene Adduct, and Peterson condensations; precursor to a stabilized Diels–Alder diene.

Technology Process of 3-Buten-2-one, 3-(trimethylsilyl)-

There total 10 articles about 3-Buten-2-one, 3-(trimethylsilyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 49.0%

: 10111-13-4
(E/Z)-1-methyl-1-propenyltrimethylsilane

: 43209-86-5
3-trimethylsilyl-3-buten-2-one

Guidance literature:: With pyridine; dmap; 5E-4 M TPP; oxygen; acetic anhydride; In acetic acid methyl ester; at -5 ℃; for 4.5h; Irradiation; in a test tube;
DOI:10.1055/s-1994-25433

Reference yield: 42.0%

: 87241-31-4
Me₃SnC(SiMe₃)CH₂

: 75-36-5
acetyl chloride

: 43209-86-5
3-trimethylsilyl-3-buten-2-one

Guidance literature:: trans benzyl(chloro)bis(triphenylphosphine)palladium(II); In benzene; for 24h; Heating;
DOI:10.1016/S0040-4039(00)81925-5

Reference yield: 32.0%

: 66374-47-8
3-trimethylsilanyl-but-3-en-2-ol

: 43209-86-5
3-trimethylsilyl-3-buten-2-one

: 85558-68-5,89537-60-0,89537-62-2,133285-66-2
1-(2-Trimethylsilanyl-oxiranyl)-ethanol

Guidance literature:: With 3,3-dimethyldioxirane; In dichloromethane; acetone; for 3.5h; Ambient temperature;
DOI:10.1016/00404-0399(50)0960K-