1-fluorophenanthrene

Base Information

• Chemical Name: 1-fluorophenanthrene
• CAS No.: 440-38-0
• Molecular Formula: C14H9F
• Molecular Weight: 196.224
• Mol file: 440-38-0.mol

Synonyms:

Chemical Property of 1-fluorophenanthrene

Chemical Property:

• Vapor Pressure: 0.000165mmHg at 25°C

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1-fluorophenanthrene

There total 2 articles about 1-fluorophenanthrene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 16.0%

2-fluorostilbene (64345-69-3) → phenanthrene (85-01-8) + 1-fluorophenanthrene (440-38-0)

Guidance literature:

In acetonitrile; for 48h; Solvent; Overall yield = 0.121 g; UV-irradiation;

DOI:10.1002/chem.201502473

Reference yield:

N-((2-fluorophenyl)sulfonyl)-N-methyl-3-phenylpropiolamide → 1-fluorophenanthrene (440-38-0) + (2-(2-fluorophenyl)ethynyl)benzene (29778-27-6)

Guidance literature:

With morpholine; In toluene; at 20 ℃; for 1h; Overall yield = 93 %; regioselective reaction; UV-irradiation;

DOI:10.1039/c7ra00193b

upstream raw materials:

2-fluorostilbene

Refernces

• 1、 Li, Zhe,Twieg, Robert J.. "Photocyclodehydrofluorination". supporting information. p. 15534 - 15539. Retrieved 2015/11/03.