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85-01-8

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85-01-8 Usage

General Description

Phenanthrene is a polycyclic aromatic hydrocarbon (PAH) composed of three fused benzene rings. It is a commonly occurring compound in fossil fuels, coal tar, and crude oil. Phenanthrene can be produced through the incomplete combustion of organic materials such as wood, tobacco, and petroleum products. It has a wide range of industrial applications, including its use as a precursor in the production of dyes, fungicides, and herbicides. Phenanthrene is also a known environmental pollutant, with potential carcinogenic and mutagenic properties, and has been identified as a priority pollutant by the United States Environmental Protection Agency. Efforts to mitigate its impact on the environment and human health include the development of methods to monitor and reduce its presence in air, water, and soil.

Check Digit Verification of cas no

The CAS Registry Mumber 85-01-8 includes 5 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 2 digits, 8 and 5 respectively; the second part has 2 digits, 0 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 85-01:
(4*8)+(3*5)+(2*0)+(1*1)=48
48 % 10 = 8
So 85-01-8 is a valid CAS Registry Number.
InChI:InChI=1/C14H10/c1-3-7-13-11(5-1)9-10-12-6-2-4-8-14(12)13/h1-10H

85-01-8 Well-known Company Product Price

  • Brand
  • (Code)Product description
  • CAS number
  • Packaging
  • Price
  • Detail
  • Alfa Aesar

  • (L01921)  Phenanthrene, 98%   

  • 85-01-8

  • 50g

  • 464.0CNY

  • Detail
  • Alfa Aesar

  • (L01921)  Phenanthrene, 98%   

  • 85-01-8

  • 250g

  • 1623.0CNY

  • Detail
  • Alfa Aesar

  • (A19646)  Phenanthrene, tech. 90%   

  • 85-01-8

  • 100g

  • 609.0CNY

  • Detail
  • Alfa Aesar

  • (A19646)  Phenanthrene, tech. 90%   

  • 85-01-8

  • 500g

  • 2275.0CNY

  • Detail
  • Alfa Aesar

  • (A19646)  Phenanthrene, tech. 90%   

  • 85-01-8

  • 2500g

  • 9552.0CNY

  • Detail
  • Sigma-Aldrich

  • (73338)  Phenanthrene  certified reference material, TraceCERT®

  • 85-01-8

  • 73338-100MG

  • 1,075.23CNY

  • Detail
  • Aldrich

  • (695114)  Phenanthrene  sublimed grade, ≥99.5%

  • 85-01-8

  • 695114-1G

  • 390.78CNY

  • Detail
  • Aldrich

  • (695114)  Phenanthrene  sublimed grade, ≥99.5%

  • 85-01-8

  • 695114-5G

  • 1,329.12CNY

  • Detail
  • Supelco

  • (48661)  Phenanthrenesolution  certified reference material, 200 μg/mL in methylene chloride

  • 85-01-8

  • 000000000000048661

  • 272.61CNY

  • Detail
  • Supelco

  • (40079)  Phenanthrenesolution  certified reference material, 5000 μg/mL in methanol

  • 85-01-8

  • 000000000000040079

  • 533.52CNY

  • Detail
  • Supelco

  • (48569)  Phenanthrene  analytical standard, for environmental analysis

  • 85-01-8

  • 000000000000048569

  • 1,069.38CNY

  • Detail
  • Aldrich

  • (P11409)  Phenanthrene  98%

  • 85-01-8

  • P11409-25G

  • 733.59CNY

  • Detail

85-01-8SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name phenanthrene

1.2 Other means of identification

Product number -
Other names PHENANTHRINE

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:85-01-8 SDS

85-01-8Relevant articles and documents

Photochemistry of supramolecular complex formed by trans-stilbene and the metal-organic coordination polymer

Semionova, Veronica V.,Glebov, Evgeni M.,Korolev, Valeri V.,Sapchenko, Sergey A.,Samsonenko, Denis G.,Fedin, Vladimir P.

, p. 342 - 348 (2014)

Supramolecular adduct consisting from the metal-organic framework (MOF) [Zn4(dmf)(ur)2(ndc)4] (ndc2- is 2,6-naphtalenedicarboxylate, ur is urotropin, and dmf is N,N'-dimethylformamide) and trans-stilbene was synthesized and its photochemistry was studied. The quantum yield of trans-cis photoisomerization of stilbene in adduct (0.2) was found to be an order of magnitude higher than for crystalline trans-stilbene and comparable with that in organic solvents. The results demonstrate that the creation of MOFs adducts with organic photochroms is a prospective approach for the creation of new hybrid photochromic materials.

Standard enthalpies of formation of phenanthrene and naphthacene

Nagano, Yatsuhisa

, p. 377 - 383 (2002)

Standard enthalpies of combustion of phenanthrene and naphthacene were determined to be -(7048.7 ± 0.9) kJ·mol-1 and -(9005.1 ± 1.8) kJ·mol-1, respectively, by means of high-precision micro-combustion calorimetry. The former result a

Bavin

, p. 1227 (1960)

Mallory et al.

, p. 4361 (1962)

Polycyclic arene episulfides. Attempted synthesis, molecular orbital calculations and comparison with arene oxides

Zoller, Uri,Shakkour, Elias,Pastersky, Irine,Sklenak, Stepan,Apeloig, Yitzhak

, p. 14283 - 14300 (1998)

In pursuit of the elusive polycyclic arene episulfides, the synthesis of phenanthrene-9,10-episulfide (5b) was attempted. However, the reactions of phenanthrene-9,10-oxide and of phenanthrene with sulfur transfer agents and of 5,7-dihydrodibenzo[c,e]thiepine (9) with butyllithium did not afford 5b, although its intermediacy could be detected by NMR and inferred from the products isolated. Quantum-mechanical ab initio and density functional methods were used to calculate the thermodynamic stability of representative arene episulfides and arene oxides. The arene episulfides were found to be thermodynamically significantly less stable than the corresponding oxides, towards elimination of sulfur and oxygen respectively. K-region arene episulfides are found to be thermodynamically more stable towards sulfur extrusion than their bay-region isomers. The thermodynamic stabilities of analogous arene oxides and arene episulfides parallel each other, and the relative thermodynamic stabilities of arene oxides and episulfides can be deduced from the degree of the aromatic character of the rings which do not carry the heteroatom.

Synthesis of new furan polycycles via photochemical reaction in neutral and acidic medium

Kuzmi?, ?eljka,?kori?,Marini?, ?eljko,Vuk, Dragana

, p. 611 - 618 (2019)

New furan derivatives of o-divinylbenzenes were synthesized and their photochemical reactivity has been investigated in neutral and acidic medium. Depending of the structure of the starting materials and pH value, the new cyclization (11, 16, 20), cycloaddiotion (12, 13, endo-17, exo-18), electrocyclization (21, 22) and dimeric (15, 19) products were isolated. While photochemical investigation in neutral medium showed that the main intramolecular process is cycloaddition, in the case of acidic photochemistry, due to the protonation of the starting molecule, electrocyclization process comes to expression and formation of dihydronaphtalene products 21 and 22.

-

Bradsher,Wert

, p. 2806 (1940)

-

Bicyclo[2.2.1]heptan-1-ylcarbene can ring expand

Ruck, Rebecca T.,Jones Jr., Maitland

, p. 4433 - 4436 (1998)

Generation of bicyclo[2.2.1]heptan-1-ylcarbene from a hydrocarbon precursor avoids the problems that attend generation from nitrogenous molecules and allows the determination that such carbenes can ring expand to bridgehead alkenes.

Srinivasan,Powers

, p. 1355 (1963)

Ni-catalyzed reductive decyanation of nitriles with ethanol as the reductant

Wu, Ke,Ling, Yichen,Sun, Nan,Hu, Baoxiang,Shen, Zhenlu,Jin, Liqun,Hu, Xinquan

supporting information, p. 2273 - 2276 (2021/03/09)

A nickel-catalyzed reductive decyanation of aromatic nitriles has been developed, in which the readily available and abundant ethanol was applied as the hydride donor. Various functional groups on the aromatic rings, such as alkoxyl, amino, imino and amide, were compatible in this catalytic protocol. Heteroaryl, benzylic and alkenyl nitriles were also tolerated. Mechanistic investigation indicated that ethanol provided hydride efficientlyviaβ-hydride elimination in this reductive decyanation.

A Bottleable Imidazole-Based Radical as a Single Electron Transfer Reagent

Das, Arpan,Ahmed, Jasimuddin,Rajendran,Adhikari, Debashis,Mandal, Swadhin K.

, p. 1246 - 1252 (2020/12/21)

Reduction of 1,3-bis(2,6-diisopropylphenyl)-2,4-diphenyl-1H-imidazol-3-ium chloride (1) resulted in the formation of the first structurally characterized imidazole-based radical 2. 2 was established as a single electron transfer reagent by treating it with an acceptor molecule tetracyanoethylene. Moreover, radical 2 was utilized as an organic electron donor in a number of organic transformations such as in activation of an aryl-halide bond, alkene hydrosilylation, and in catalytic reduction of CO2 to methoxyborane, all under ambient temperature and pressure.

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