Acetic acid, (phenylthio)(triphenylphosphoranylidene)-, methyl ester

Base Information

Chemical Name:Acetic acid, (phenylthio)(triphenylphosphoranylidene)-, methyl ester
CAS No.:442691-87-4
Molecular Formula:C₂₇H₂₃O₂PS
Molecular Weight:442.518
Hs Code.:
DSSTox Substance ID:DTXSID30476037
Nikkaji Number:J1.694.524B
Wikidata:Q82306961

Synonyms:DTXSID30476037;Acetic acid, (phenylthio)(triphenylphosphoranylidene)-, methyl ester

Suppliers and Price of Acetic acid, (phenylthio)(triphenylphosphoranylidene)-, methyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Acetic acid, (phenylthio)(triphenylphosphoranylidene)-, methyl ester

Chemical Property:

XLogP3:6.5
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:7
Exact Mass:442.11563814
Heavy Atom Count:31
Complexity:569

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC(=O)C(=P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3)SC4=CC=CC=C4

Technology Process of Acetic acid, (phenylthio)(triphenylphosphoranylidene)-, methyl ester

There total 4 articles about Acetic acid, (phenylthio)(triphenylphosphoranylidene)-, methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 108-98-5
thiophenol

: 1-phenyliodonium[methyl (triphenylphosphoranylidene)acetate] tosylate

: 442691-87-4
phenylsulfanyl-(triphenyl-λ⁵-phosphanylidene)-acetic acid methyl ester

Guidance literature:: With n-butyllithium; In hexane; dichloromethane; at 0 - 20 ℃;
DOI:10.1021/jo026604y

Reference yield:

: 21204-67-1,2605-67-6
methyl (triphenylphosphoranylidene)acetate

: 442691-87-4
phenylsulfanyl-(triphenyl-λ⁵-phosphanylidene)-acetic acid methyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 47 percent / CH₂Cl₂ / 20 °C

2: BuLi / CH₂Cl₂; hexane / 0 - 20 °C

With n-butyllithium; In hexane; dichloromethane;
DOI:10.1021/jo026604y