2973-86-6

Basic information

• Product Name: LITHIUM THIOPHENOXIDE
• Synonyms: LITHIUM THIOPHENOXIDE;Lithium thiophenolate solution;thiophenol lithium salt solution;THIOPHENOL LITHIUM SALT SOLUTION, ~1 M I N THF;LITHIUM THIOPHENOXIDE, 1.0M SOLUTION IN TETRAHYDROFURAN;thiophenol lithium salt;Lithium thiophenolate, 0.6M solution in THF, AcroSeal;Lithium thiophenoxide (1M THF solution)
• CAS NO: 2973-86-6
• Molecular Formula: C₆H₅LiS
• Molecular Weight: 116.11
• Mol File: 2973-86-6.mol
• Article Data: 7

Chemical Properties

• Boiling Point: 67 °C
• Flash Point: 1 °F
• Appearance: /
• Density: 0.934 g/mL at 25 °C
• BRN: 3597301
• CAS DataBase Reference: LITHIUM THIOPHENOXIDE(CAS DataBase Reference)
• NIST Chemistry Reference: LITHIUM THIOPHENOXIDE(2973-86-6)
• EPA Substance Registry System: LITHIUM THIOPHENOXIDE(2973-86-6)

Safety Data

• Hazard Codes: F,C
• Statements: 11-19-34-40-37
• Safety Statements: 16-26-29-33-36/37/39-45
• RIDADR: UN 2924 3/PG 2
• WGK Germany: 1
• F: 3-10
• Hazardous Substances Data: 2973-86-6(Hazardous Substances Data)

Usage

General Description

Lithium thiophenoxide is a chemical compound that consists of lithium and thiophenol. It is commonly used as a reagent in organic synthesis, particularly in the formation of carbon-carbon bonds. It is a strong base and nucleophile, making it useful in a variety of reactions such as cross-coupling reactions and nucleophilic aromatic substitution. Lithium thiophenoxide has also been studied for its potential applications in pharmaceutical and agrochemical industries. Its unique properties and reactivity make it a valuable intermediate in the production of a wide range of organic compounds.

Upstream product

• 98585-81-0 bicyclo<1.1.1>pentyl phenyl sulfide 
• 108-98-5 thiophenol 
• 124-38-9 carbon dioxide 
• 4148-93-0 2-phenyl-2-propyl phenyl sulfide 
• 930-69-8 sodium thiophenolate 
• 40390-78-1 [(1-phenylethyl)thio]benzene 
• 13112-47-5 1,1'-[2-(phenylsulfanyl)-1,1-ethanediyl]dibenzene 
• 4148-81-6 1-(1-methyl-2-phenylsulfanyl-ethyl)-benzene 
• 5023-67-6 4-methoxybenzyl phenyl sulfide 
• 13865-49-1 [2-(phenylsulfanyl)ethyl]benzene 
• 60731-09-1 (1,1-diphenylethyl)(phenyl)sulfane 
• 5848-60-2 cinnamyl(phenyl)sulfide 
• 831-91-4 Benzyl phenyl sulfide 
• 882-33-7 diphenyldisulfane 

Downstream Products

• 71558-12-8 (2E,6E,10E)-3,7,11-Trimethyl-12-phenylsulfanyl-dodeca-2,6,10-trienoic acid methyl ester 
• 24760-10-9 n-Butyl(triphenylmethyl)sulfane 
• 87957-90-2 2,2-Dimethyl-c-3-phenyl-t-3-(phenylthio)-r-1-cyclopropancarbonsaeure-tert-butylester 
• 87957-90-2 2,2-Dimethyl-t-3-phenyl-c-3-(phenylthio)-r-1-cyclopropancarbonsaeure-tert-butylester 
• 882-33-7 diphenyldisulfane 
• 87957-92-4 2,2,3-Triphenyl-c-3-(phenylthio)-r-1-cyclopropancarbonsaeure-tert-butylester 
• 87957-92-4 2,2,3-Triphenyl-t-3-(phenylthio)-r-1-cyclopropancarbonsaeure-tert-butylester 
• 109585-28-6 anti-2-nitro-(3-phenylthio)butane 
• 100-68-5 methyl-phenyl-thioether 
• 52938-70-2 δ-phenylthio-γ-butyrolactone 
• 16222-10-9 1-phenyl-2-(phenylthio)ethanone 
• 65756-04-9 trans-(±)-2-(phenylthio)cyclopentanol 
• 162708-82-9 3,3,9-trimethyl-8-phenylthiomethyl-1,5-dioxaspiro<5.5>undec-8-ene 

Relevant articles and documents

Efficient synthesis of carborane azo derivatives and their reactivity

An iridium(iii)-catalyzed C-N-bond-forming direct synthesis of carborane azo derivatives was developed. The reaction of o-carborane monocarboxylate with aryldiazonium salt in the presence of a catalytic amount of [Cp?IrCl2]2 and NaOA

Reductive lithiation of alkyl phenyl sulfides in diethyl ether. A ready access to α,α-dialkylbenzyllithiums

Diethyl ether is a convenient solvent for the conversion of benzylic phenyl sulfides to the corresponding organolithiums by an uncatalyzed reductive metalation, while catalysis by naphthalene is required to achieve the same reaction for alkyl phenyl sulfides. The addition of magnesium 2-ethoxyethoxide to solutions of unstable alkyllithiums prepared in this way provides storable reagents.

A method for the determination of the degree of association of organolithium compounds in liquid ammonia

A method for carrying out cryoscopy in liquid ammonia is presented.The degrees of association of some organolithium compounds in liquid ammonia have been determined.