Benzenamine, 4-ethenyl-N-(4-ethenylphenyl)-N-phenyl-

Base Information

• Chemical Name: Benzenamine, 4-ethenyl-N-(4-ethenylphenyl)-N-phenyl-
• CAS No.: 442904-28-1
• Molecular Formula: C22H19N
• Molecular Weight: 297.4
• Mol file: 442904-28-1.mol

Synonyms:4,4'-bis(vinylphenyl)-N-phenylamine;N,N'-bis(4-vinylphenyl)benzenamine;4,4'-bisvinylphenyl-N-phenylamine;

Chemical Property of Benzenamine, 4-ethenyl-N-(4-ethenylphenyl)-N-phenyl-

Chemical Property:

• Melting Point: 112 - 115 °C
• PSA: 3.24000
• LogP: 6.44240

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Benzenamine, 4-ethenyl-N-(4-ethenylphenyl)-N-phenyl-

There total 3 articles about Benzenamine, 4-ethenyl-N-(4-ethenylphenyl)-N-phenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

4,4'-diformyltriphenylamine (53566-95-3) + Methyltriphenylphosphonium bromide (1779-49-3) → N-phenyl-4-vinyl-N-(4-vinylphenyl)aniline (442904-28-1)

Guidance literature:

Methyltriphenylphosphonium bromide; With potassium tert-butylate; In tetrahydrofuran; at 0 ℃; for 0.25h;

4,4'-diformyltriphenylamine; In tetrahydrofuran; at 20 ℃; for 3h;

DOI:10.1039/c4tc00706a

Reference yield: 73.0%

4,4'-diformyltriphenylamine (53566-95-3) + methyl-triphenylphosphonium iodide (2065-66-9) → N-phenyl-4-vinyl-N-(4-vinylphenyl)aniline (442904-28-1)

Guidance literature:

With potassium tert-butylate; In tetrahydrofuran; at 25 ℃; for 24h; Inert atmosphere; Schlenk technique;

DOI:10.1039/c6nj02720b

Reference yield: 41.0%

tri-n-butyl(vinyl)tin (7486-35-3) + N,N-bis(4-bromophenyl)aniline (81090-53-1) → N-phenyl-4-vinyl-N-(4-vinylphenyl)aniline (442904-28-1)

Guidance literature:

With bis-triphenylphosphine-palladium(II) chloride; 2,6-di-tert-butylphenol; In toluene; at 100 ℃; Inert atmosphere;

DOI:10.1002/pola.27334

upstream raw materials:

4,4'-diformyltriphenylamine

methyl-triphenylphosphonium iodide

Methyltriphenylphosphonium bromide

tri-n-butyl(vinyl)tin

Downstream raw materials:

4,4'-bis[4-(2,2':6',2'’-terpyridinyl)] styryl triphenylamine