Carbonic acid, 1,1-dimethylethyl 1-phenyl-2-propenyl ester

Base Information

Chemical Name:Carbonic acid, 1,1-dimethylethyl 1-phenyl-2-propenyl ester
CAS No.:444575-79-5
Molecular Formula:C14H18O3
Molecular Weight:234.295
Hs Code.:

Synonyms:tert-butyl (1-phenylallyl) carbonate;(+/-)-tert-butyl 1-phenylprop-2-en-1-yl carbonate;tert-butyl (1-phenylallyl)carbonate;

Suppliers and Price of Carbonic acid, 1,1-dimethylethyl 1-phenyl-2-propenyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 1 raw suppliers

Chemical Property of Carbonic acid, 1,1-dimethylethyl 1-phenyl-2-propenyl ester

Chemical Property:

Boiling Point:295.4±29.0 °C(Predicted)
PSA：35.53000
Density:1.031±0.06 g/cm3(Predicted)
LogP:3.86540

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Carbonic acid, 1,1-dimethylethyl 1-phenyl-2-propenyl ester

There total 3 articles about Carbonic acid, 1,1-dimethylethyl 1-phenyl-2-propenyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 24424-99-5
di-tert-butyl dicarbonate

: 4393-06-0
1-Phenyl-2-propen-1-ol

: 444575-79-5
carbonic acid 1,1-dimethylethyl 1-phenyl-2-propenyl ester

Guidance literature:: 1-Phenyl-2-propen-1-ol; With sodium hydride; In tetrahydrofuran; mineral oil; at 20 ℃; for 1h;

di-tert-butyl dicarbonate; In tetrahydrofuran; mineral oil; at 20 ℃;
DOI:10.1021/jo801874r

Reference yield:

: 100-52-7
benzaldehyde

: 444575-79-5
carbonic acid 1,1-dimethylethyl 1-phenyl-2-propenyl ester

Guidance literature:: Multi-step reaction with 2 steps

1.1: tetrahydrofuran / 0 - 20 °C

2.1: n-butyllithium / tetrahydrofuran / 0.5 h / 0 °C

2.2: 20 °C

With n-butyllithium; In tetrahydrofuran;
DOI:10.1021/jacs.6b11205

Reference yield:

: 24424-99-5
di-tert-butyl dicarbonate

: 100-52-7
benzaldehyde

: 444575-79-5
carbonic acid 1,1-dimethylethyl 1-phenyl-2-propenyl ester

Guidance literature:: benzaldehyde; allylmagnesium halide; Inert atmosphere;

di-tert-butyl dicarbonate; With alkali metal base; Inert atmosphere;
DOI:10.1021/jacs.5b01951