4-Aminoacenaphthene

Base Information

• Chemical Name: 4-Aminoacenaphthene
• CAS No.: 4657-97-0
• Molecular Formula: C₁₂H₁₁N
• Molecular Weight: 169.226
• Hs Code.: 2921499090
• Mol file: 4657-97-0.mol

Synonyms:4-Acenaphthylenamine, 1,2-dihydro-;Acenaphthen-4-ylamin;4-Amino-acenaphthen;4-aminoacenaphthene;4-Acenaphthylenamine,1,2-dihydro;acenaphthen-4-ylamine;4-Acenaphthenamin;1,2-dihydro-4-acenaphthylenamine;

Chemical Property of 4-Aminoacenaphthene

Chemical Property:

• PSA: 26.02000
• LogP: 3.10180

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 4-Aminoacenaphthene

There total 7 articles about 4-Aminoacenaphthene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4-nitro-acenaphthene (1015-74-3) → 4-aminoacenaphthene (4657-97-0)

Guidance literature:

With ethyl acetate; platinum; Hydrogenation;

DOI:10.1039/jr9540002853

Reference yield:

4-nitro-acenaphthen-5-ylamine (4657-95-8) → 4-aminoacenaphthene (4657-97-0)

Guidance literature:

Multi-step reaction with 2 steps

1: acetic acid; H₂SO₄; Na₂NO₂ / Erwaermen des Reaktionsgemisches mit Cu₂O und Methanol

2: platinum; ethyl acetate / Hydrogenation

With sulfuric acid; acetic acid; ethyl acetate; platinum; sodium nitrite;

DOI:10.1039/jr9540002853

Reference yield:

5-acetamidoacenaphthene (4657-94-7) → 4-aminoacenaphthene (4657-97-0)

Guidance literature:

Multi-step reaction with 3 steps

1: (i) aq. HNO₃, AcOH, (ii) aq. H₂SO₄, EtOH

2: (i) NaNO₂, H₂SO₄, AcOH, (ii) CuSO₄, aq. H₃PO₂, EtOH

3: N₂H₄*H₂O / Pd-C / ethanol / Heating

With hydrazine hydrate; palladium on activated charcoal; In ethanol;

DOI:10.1016/S0040-4020(01)96925-X

upstream raw materials:

4-nitro-acenaphthene

N-acenaphthen-4-yl-acetamide

hydrogenchloride

4-nitro-acenaphthen-5-ylamine

Downstream raw materials:

4-Benzamido-acenaphthen

1,2-dihydroacenaphthylen-4-ol

4-Benzoyl-acenaphthen

4-<α-Hydroxy-benzyl>-acenaphthylen