Borazine,1,2,3,4,5,6-hexahydro-

Base Information

• Chemical Name: Borazine,1,2,3,4,5,6-hexahydro-
• CAS No.: 13871-09-5
• Molecular Formula: B₃H₁₂N₃
• Molecular Weight: 86.5484
• Mol file: 13871-09-5.mol

Synonyms:

Chemical Property of Borazine,1,2,3,4,5,6-hexahydro-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Borazine,1,2,3,4,5,6-hexahydro-

There total 15 articles about Borazine,1,2,3,4,5,6-hexahydro- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 27.0%

ammonia borane → cyclotriborane (13871-09-5) + borazine (6569-51-3)

Guidance literature:

In diethylene glycol; 30 min, 130°C; identified by 11B NMR spectroscopy;;

DOI:10.1016/S0020-1693(00)87499-X

Reference yield: 18.0%

sodium tetrahydroborate (16940-66-2) + ammonium sulfate → borane-ammonia complex (10043-11-5) + μ-aminodiborane (75885-49-3) + cyclotriborane (13871-09-5) + borazine (6569-51-3)

Guidance literature:

In further solvent(s); byproducts: H2; under Ar atm.; grinded (NH4)2SO4 and NaBH4 stirred in triglyme heated to120°C for 30 min, treated at this temp. until the cease of gases released; mixt. distd. several times under high vac., collected in liq. N2 traps, condensed at -78°C; detd. by XRD, NMR, mass-spectrometry;

DOI:10.1016/j.ica.2010.10.030

Reference yield:

borane-ammonia complex (10043-11-5) → cyclotriborane (13871-09-5) + borazine (6569-51-3)

Guidance literature:

[ReBr(NO)(PCy₃)(H)(1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene)]; In tetrahydrofuran; byproducts: H2; (N2); std. Schlenk technique; soln. of B compd. in THF was heated at 65°C for 4 h in presence of Re complex; NMR monitoring;

DOI:10.1021/om900458e

upstream raw materials:

sodium tetrahydroborate

borane-ammonia complex

Downstream raw materials:

borazine