1-{[tert-Butyl(diphenyl)silyl]oxy}-5-methylhex-5-en-3-ol

Base Information

Chemical Name:1-{[tert-Butyl(diphenyl)silyl]oxy}-5-methylhex-5-en-3-ol
CAS No.:479485-75-1
Molecular Formula:C23H32O2Si
Molecular Weight:368.58400
Hs Code.:
DSSTox Substance ID:DTXSID90579775
Nikkaji Number:J1.808.309D
Mol file:479485-75-1.mol

Synonyms:479485-75-1;DTXSID90579775;1-{[tert-Butyl(diphenyl)silyl]oxy}-5-methylhex-5-en-3-ol

Suppliers and Price of 1-{[tert-Butyl(diphenyl)silyl]oxy}-5-methylhex-5-en-3-ol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1-{[tert-Butyl(diphenyl)silyl]oxy}-5-methylhex-5-en-3-ol

Chemical Property:

PSA：29.46000
LogP:4.28020
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:9
Exact Mass:368.217156794
Heavy Atom Count:26
Complexity:410

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC(=C)CC(CCO[Si](C1=CC=CC=C1)(C2=CC=CC=C2)C(C)(C)C)O

Technology Process of 1-{[tert-Butyl(diphenyl)silyl]oxy}-5-methylhex-5-en-3-ol

There total 5 articles about 1-{[tert-Butyl(diphenyl)silyl]oxy}-5-methylhex-5-en-3-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 1458-98-6
2-methyl-3-bromo-1-propene

: 112897-03-7
3-(tert-butyldiphenylsilyloxy)-1-propanal

: 479485-75-1
1-((tertbutyldiphenylsilyl)oxy)-5-methylhex-5-en-3-ol

Guidance literature:: indium; In tetrahydrofuran; water; at 0 - 20 ℃; for 15h;
DOI:10.1016/S0040-4039(02)01666-0

Reference yield: 58.0%

: 112897-03-7
3-(tert-butyldiphenylsilyloxy)-1-propanal

: 563-47-3
3-Chloro-2-methylpropene

: 479485-75-1
1-((tertbutyldiphenylsilyl)oxy)-5-methylhex-5-en-3-ol

Guidance literature:: 3-Chloro-2-methylpropene; With magnesium; In tetrahydrofuran; at 0 ℃; for 1.5h;

3-(tert-butyldiphenylsilyloxy)-1-propanal; In tetrahydrofuran; at 22 ℃; for 2.58333h;
DOI:10.1021/ol500835f

Reference yield:

: 112897-03-7
3-(tert-butyldiphenylsilyloxy)-1-propanal

: 167773-10-6
4,4,5,5-tetramethyl-2-(2-methylallyl)-1,3,2-dioxaborolane

: 479485-75-1
1-((tertbutyldiphenylsilyl)oxy)-5-methylhex-5-en-3-ol

Guidance literature:: 3-(tert-butyldiphenylsilyloxy)-1-propanal; 4,4,5,5-tetramethyl-2-(2-methylallyl)-1,3,2-dioxaborolane; With scandium tris(trifluoromethanesulfonate); In dichloromethane; at -78 ℃; for 16h;

With diisobutylaluminium hydride; In dichloromethane; toluene; at -78 ℃; for 0.5h;
DOI:10.1021/ja036807j