Tris(m-nitrophenyl)phosphine oxide

Base Information

• Chemical Name: Tris(m-nitrophenyl)phosphine oxide
• CAS No.: 31638-89-8
• Molecular Formula: C18H12 N3 O7 P
• Molecular Weight: 413.283
• Hs Code.: 2904209090
• European Community (EC) Number: 250-745-2
• NSC Number: 157377
• UNII: UJU4A3U06O
• DSSTox Substance ID: DTXSID0021703
• Nikkaji Number: J278.162J
• Wikidata: Q27291110
• Mol file: 31638-89-8.mol

Synonyms:Tris(m-nitrophenyl)phosphine oxide;Tris(3-nitrophenyl)phosphine oxide;31638-89-8;EINECS 250-745-2;tris(3-nitrophenyl)phosphane oxide;UNII-UJU4A3U06O;UJU4A3U06O;NSC-157377;1-bis(3-nitrophenyl)phosphoryl-3-nitrobenzene;phosphorane, tris(3-nitrophenyl)-, oxide;SCHEMBL8408187;DTXSID0021703;C18H12N3O7P;Tris-(3-nitrophenyl)-phosphinoxid;C18-H12-N3-O7-P;NSC157377;STL503706;AKOS024430195;NSC 157377;Phosphine oxide, tris(3-nitrophenyl)-;LS-184858;TRIS-(3-NITROPHENYL)PHOSPHINE OXIDE;PHOSPHINE OXIDE, TRIS(M-NITROPHENYL)-;1-bis(3-nitrophenyl)phosphoryl-3-nitro-benzene;Q27291110

Chemical Property of Tris(m-nitrophenyl)phosphine oxide

Chemical Property:

• Vapor Pressure: 5.31E-16mmHg at 25°C
• Melting Point: 235 °C
• Boiling Point: 648.7°Cat760mmHg
• Flash Point: 346.2°C
• PSA: 164.34000
• Density: 1.53g/cm³
• LogP: 4.62020
• XLogP3: 3.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 7
• Rotatable Bond Count: 3
• Exact Mass: 413.04128673
• Heavy Atom Count: 29
• Complexity: 596

Purity/Quality:

99% ^*data from raw suppliers

TRIS(3-NITROPHENYL)PHOSPHINE OXIDE Aldrich ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC(=CC(=C1)P(=O)(C2=CC=CC(=C2)[N+](=O)[O-])C3=CC=CC(=C3)[N+](=O)[O-])[N+](=O)[O-]

Technology Process of Tris(m-nitrophenyl)phosphine oxide

There total 5 articles about Tris(m-nitrophenyl)phosphine oxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

Triphenylphosphine oxide (791-28-6) → tris-(m-nitrophenyl)phosphinoxide (31638-89-8)

Guidance literature:

With nitric acid; In sulfuric acid; at 0 - 20 ℃; for 4h;

DOI:10.1016/j.tetlet.2017.10.061

Reference yield:

→ tris-(m-nitrophenyl)phosphinoxide (31638-89-8)

Guidance literature:

With sulfuric acid; nitric acid; ueber mehrere Stufen;

Reference yield:

triphenylphosphine (603-35-0) → tris-(m-nitrophenyl)phosphinoxide (31638-89-8)

Guidance literature:

upstream raw materials:

triphenylphosphine

Triphenylphosphine oxide

Downstream raw materials:

tris(3-aminophenyl)phenyl phosphine oxide

Refernces

• 1、 Shabanian, Meisam,Kang, Nianjun,Liu, Jianwen,Wagenknecht, Udo,Heinrich, Gert,Wang, De-Yi. "Bio-based semi-aromatic polyamide/functional clay nanocomposites: Preparation and properties". . p. 23420 - 23427. Retrieved 2014/07/07.