3-[Di(3-aminophenyl)phosphoryl]aniline

Base Information

Chemical Name:3-[Di(3-aminophenyl)phosphoryl]aniline
CAS No.:36357-49-0
Molecular Formula:C18H18 N3 O P
Molecular Weight:323.334
Hs Code.:2921499090
European Community (EC) Number:622-250-5
DSSTox Substance ID:DTXSID80381445
Nikkaji Number:J70.215C
Wikidata:Q82172265
Mol file:36357-49-0.mol

Synonyms:3-[di(3-aminophenyl)phosphoryl]aniline;36357-49-0;tris(3-aminophenyl)phosphine oxide;3-bis(3-aminophenyl)phosphorylaniline;SCHEMBL9688354;3,3',3''-phosphoryltrianiline;DTXSID80381445;tris(3-aminophenyl) phosphine oxide;MFCD00025243;AKOS024319260

Suppliers and Price of 3-[Di(3-aminophenyl)phosphoryl]aniline

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
TRIS(3-AMINOPHENYL)PHOSPHINE OXIDE AldrichCPR
50mg
$ 144.00

American Custom Chemicals Corporation
3-[DI(3-AMINOPHENYL)PHOSPHORYL]ANILINE 95.00%
50MG
$ 727.65

Total 4 raw suppliers

Chemical Property of 3-[Di(3-aminophenyl)phosphoryl]aniline

Chemical Property:

Melting Point:248 °C
Boiling Point:668.7±55.0 °C(Predicted)
PKA:3.93±0.10(Predicted)
PSA：104.94000
Density:1.31±0.1 g/cm3(Predicted)
LogP:3.81620
XLogP3:2
Hydrogen Bond Donor Count:3
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:3
Exact Mass:323.11874920
Heavy Atom Count:23
Complexity:382

Purity/Quality:

98%,99%, ^*data from raw suppliers

TRIS(3-AMINOPHENYL)PHOSPHINE OXIDE AldrichCPR ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: Total 1 MSDS from other Authors

Useful:

Canonical SMILES:C1=CC(=CC(=C1)P(=O)(C2=CC=CC(=C2)N)C3=CC=CC(=C3)N)N

Technology Process of 3-[Di(3-aminophenyl)phosphoryl]aniline

There total 3 articles about 3-[Di(3-aminophenyl)phosphoryl]aniline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 31638-89-8
tris-(m-nitrophenyl)phosphinoxide

: 36357-49-0
tris(3-aminophenyl)phenyl phosphine oxide

Guidance literature:: With hydrazine hydrate; palladium on activated charcoal; In ethanol; at 0 - 90 ℃; for 4h; Inert atmosphere;
DOI:10.1016/j.tetlet.2017.10.061

Reference yield:

: 791-28-6
Triphenylphosphine oxide

: 36357-49-0
tris(3-aminophenyl)phenyl phosphine oxide

Guidance literature:: Multi-step reaction with 2 steps

1: nitric acid / sulfuric acid / 4 h / 0 - 20 °C

2: palladium on activated charcoal; hydrazine hydrate / ethanol / 4 h / 0 - 90 °C / Inert atmosphere

With hydrazine hydrate; palladium on activated charcoal; nitric acid; In ethanol; sulfuric acid;
DOI:10.1016/j.tetlet.2017.10.061