1,4-Dimethyl-2,3-diaza-bicyclo(2.2.2)oct-2-ene

Base Information

• Chemical Name: 1,4-Dimethyl-2,3-diaza-bicyclo(2.2.2)oct-2-ene
• CAS No.: 49570-30-1
• Molecular Formula: C8H14N2
• Molecular Weight: 138.213
• DSSTox Substance ID: DTXSID70197855
• Nikkaji Number: J465.236C
• Wikidata: Q83070609
• Mol file: 49570-30-1.mol

Synonyms:1,4-Dimethyl-2,3-diaza-bicyclo(2.2.2)oct-2-ene;49570-30-1;1,4-Dimethyl-2,3-diaza-bicyclo[2.2.2]oct-2-ene;2,3-Diazabicyclo[2.2.2]oct-2-ene,1,4-dimethyl-;DTXSID70197855;1,4-dimethyl-(2,3-diazabicyclo[2.2.2]oct-2-ene)

Chemical Property of 1,4-Dimethyl-2,3-diaza-bicyclo(2.2.2)oct-2-ene

Chemical Property:

• Vapor Pressure: 3.82mmHg at 25°C
• Boiling Point: 155.9°C at 760 mmHg
• Flash Point: 39.2°C
• Density: 1.12g/cm³
• XLogP3: 1.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 138.115698455
• Heavy Atom Count: 10
• Complexity: 156

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC12CCC(CC1)(N=N2)C

Technology Process of 1,4-Dimethyl-2,3-diaza-bicyclo(2.2.2)oct-2-ene

There total 1 articles about 1,4-Dimethyl-2,3-diaza-bicyclo(2.2.2)oct-2-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

→ 1,4-dimethyl-2,3-diaza-bicyclo[2.2.2]oct-2-ene (49570-30-1)

Guidance literature:

1,4-Dimethyl-cyclohexa-1,3-dien, Azodicarbonsaeurediethylester;

DOI:10.1021/ja01053a002

Reference yield:

1,4-dimethyl-2,3-diaza-bicyclo[2.2.2]oct-2-ene (49570-30-1) → 2,5-dimethyl-1,5-hexadiene (627-58-7)

Guidance literature:

at 272 ℃; Rate constant; Thermodynamic data; other temperature, heat of decomposition; thermolysis of 2,3-diazabicyclo<2.2.2>oct-2-ene derivatives;

DOI:10.1021/ja00362a014

Reference yield:

1,4-dimethyl-2,3-diaza-bicyclo[2.2.2]oct-2-ene (49570-30-1) → 2,5-dimethyl-1,5-hexadiene (627-58-7) + 1,4-dimethylbicyclo<2.2.0>hexane (24322-10-9)

Guidance literature:

In fluorobenzene; Product distribution; Thermodynamic data; Quantum yield; Irradiation; direct and sensitized irradiation; photholysis of 2,3-diazobicyclo<2.2.2>oct-2-ene derivatives; fluorescence quantum yields and lifetimes, effect of temperature, rate constant for fluorescence;

DOI:10.1021/ja00362a015

Downstream raw materials:

2,5-dimethyl-1,5-hexadiene

1,4-dimethylbicyclo<2.2.0>hexane

1,4-dimethylcyclohex-1-ene

para-xylene