Cyclohexene, 1,4-dimethyl-

Base Information

• Chemical Name: Cyclohexene, 1,4-dimethyl-
• CAS No.: 2808-79-9
• Molecular Formula: C8H14
• Molecular Weight: 110.199
• Mol file: 2808-79-9.mol

Synonyms:1,4-Dimethyl-1-cyclohexene;1,4-Dimethylcyclohexene

Chemical Property of Cyclohexene, 1,4-dimethyl-

Chemical Property:

• Vapor Pressure: 14mmHg at 25°C
• Melting Point: -59.4°C
• Refractive Index: 1.445
• Boiling Point: 126.7°C at 760 mmHg
• Flash Point: 11.7°C
• PSA: 0.00000
• Density: 0.8g/cm³
• LogP: 2.75270

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Cyclohexene, 1,4-dimethyl-

There total 22 articles about Cyclohexene, 1,4-dimethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

1,4-dimethylcyclohexan-1-ol (5402-28-8) → 1,4-dimethylcyclohex-1-ene (2808-79-9)

Guidance literature:

With silica gel; iron(III) chloride; for 36h; Ambient temperature;

DOI:10.1016/S0040-4020(01)96434-8

Reference yield: 90.0%

para-xylene (106-42-3) → 1,4-dimethylcyclohex-1-ene (2808-79-9) + 1,4 dimethylcyclohexane (589-90-2)

Guidance literature:

With hydrogen; 1-butyl-3-methylimidazolium Tetrafluoroborate; Rh nanoparticles stabilized by poly(NVP-co-VBIMCl); at 75 ℃; for 12h; under 30402 Torr; Product distribution;

DOI:10.1016/j.jcat.2007.05.014

Reference yield:

para-xylene (106-42-3) → trans-1,4-dimethylcyclohexane (2207-04-7) + cis-1,4-dimethylcyclohexane (624-29-3) + 1,4-dimethylcyclohex-1-ene (2808-79-9)

Guidance literature:

With Rh(allyl)3; C₆₈H₈₈O₆P₂; hydrogen; In n-heptane; at 80 ℃; for 16h; under 30003 Torr; Temperature; Pressure; stereoselective reaction; Autoclave; Glovebox;

DOI:10.1039/c3cy00388d

upstream raw materials:

formic acid

1,4-Dimethyl-cyclohexanol

trans-1,4-dimethylcyclohexan-1-ol

1,4-dimethylcyclohexan-1-ol

Downstream raw materials:

1,4-dimethyl-cyclohexane-1,2-diol

2,5-dimethyl-cyclohex-2-enone

2,5-dimethyl-1-cyclohexen-1-yl 2-methyl-1-cyclopenten-1-yl ketone

1,4 dimethylcyclohexane