4-Bromomethylphenyl-1,3,2-dioxaborolane

Base Information

Chemical Name:4-Bromomethylphenyl-1,3,2-dioxaborolane
CAS No.:488133-21-7
Molecular Formula:C9H10BBrO2
Molecular Weight:240.88900
Hs Code.:2934999090
European Community (EC) Number:974-122-6
DSSTox Substance ID:DTXSID80597160
Wikidata:Q82492658
Mol file:488133-21-7.mol

Synonyms:4-Bromomethylphenyl-1,3,2-dioxaborolane;488133-21-7;2-(4-(Bromomethyl)phenyl)-1,3,2-dioxaborolane;2-[4-(BROMOMETHYL)PHENYL]-1,3,2-DIOXABOROLANE;SCHEMBL7706050;DTXSID80597160;MFCD18447588;AKOS016016053;DB-364009;CS-0190023;D71430

Suppliers and Price of 4-Bromomethylphenyl-1,3,2-dioxaborolane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
2-[4-(Bromomethyl)phenyl]-1,3,2-dioxaborolane
100mg
$ 75.00

Chemenu
2-(4-(Bromomethyl)phenyl)-1,3,2-dioxaborolane 95+%
25g
$ 722.00

Chemenu
2-(4-(Bromomethyl)phenyl)-1,3,2-dioxaborolane 95+%
1g
$ 71.00

Chemenu
2-(4-(Bromomethyl)phenyl)-1,3,2-dioxaborolane 95+%
5g
$ 171.00

AOBChem
4-Bromomethylphenyl-1,3,2-dioxaborolane 97%
5g
$ 150.00

AOBChem
4-Bromomethylphenyl-1,3,2-dioxaborolane 97%
100g
$ 1391.00

AOBChem
4-Bromomethylphenyl-1,3,2-dioxaborolane 97%
25g
$ 502.00

Alichem
4-Bromomethylphenyl-1,3,2-dioxaborolane
1g
$ 1685.00

Alichem
4-Bromomethylphenyl-1,3,2-dioxaborolane
250mg
$ 680.00

Total 7 raw suppliers

Chemical Property of 4-Bromomethylphenyl-1,3,2-dioxaborolane

Chemical Property:

PSA：18.46000
LogP:1.32350
Storage Temp.:2-8°C
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:2
Exact Mass:239.99572
Heavy Atom Count:13
Complexity:154

Purity/Quality:

98% ^*data from raw suppliers

2-[4-(Bromomethyl)phenyl]-1,3,2-dioxaborolane ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:B1(OCCO1)C2=CC=C(C=C2)CBr

Technology Process of 4-Bromomethylphenyl-1,3,2-dioxaborolane

There total 2 articles about 4-Bromomethylphenyl-1,3,2-dioxaborolane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 69519-10-4
2-(p-tolyl)-1,3,2-dioxaborolane

: 488133-21-7
2-(4-(bromomethyl)phenyl)-1,3,2-dioxaborolane

Guidance literature:: With N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile); In tetrachloromethane; for 18h; Reflux;
DOI:10.1177/1747519820960692

Reference yield:

: 5720-05-8
4-methylphenylboronic acid

: 488133-21-7
2-(4-(bromomethyl)phenyl)-1,3,2-dioxaborolane

Guidance literature:: Multi-step reaction with 2 steps

1: toluene / Dean-Stark; Reflux

2: 2,2'-azobis(isobutyronitrile); N-Bromosuccinimide / tetrachloromethane / 18 h / Reflux

With N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile); In tetrachloromethane; toluene;
DOI:10.1177/1747519820960692