Ethyl 2-methyl-1,3-dioxolane-2-carboxylate

Base Information

Chemical Name:Ethyl 2-methyl-1,3-dioxolane-2-carboxylate
CAS No.:56624-93-2
Molecular Formula:C₇H₁₂O₄
Molecular Weight:160.17
Hs Code.:
NSC Number:163401
DSSTox Substance ID:DTXSID80303905
Wikidata:Q82049405

Synonyms:ethyl 2-methyl-1,3-dioxolane-2-carboxylate;56624-93-2;NSC163401;SCHEMBL13609676;DTXSID80303905;AKOS016042554;NSC-163401

Suppliers and Price of Ethyl 2-methyl-1,3-dioxolane-2-carboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 4 raw suppliers

Chemical Property of Ethyl 2-methyl-1,3-dioxolane-2-carboxylate

Chemical Property:

Vapor Pressure:0.233mmHg at 25°C
Boiling Point:206.8°C at 760 mmHg
Flash Point:81.4°C
Density:1.117g/cm³
XLogP3:0.3
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:3
Exact Mass:160.07355886
Heavy Atom Count:11
Complexity:149

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCOC(=O)C1(OCCO1)C

Technology Process of Ethyl 2-methyl-1,3-dioxolane-2-carboxylate

There total 2 articles about Ethyl 2-methyl-1,3-dioxolane-2-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 617-35-6
2-oxo-propionic acid ethyl ester

: 107-21-1
ethylene glycol

: 56624-93-2
ethoxycarbonyl-2 methyl-2 dioxolanne-1,3

Guidance literature:: With boron trifluoride diethyl etherate; acetic acid; In dichloromethane; at 0 - 40 ℃; for 16h;

Reference yield:

: 617-35-6
2-oxo-propionic acid ethyl ester

: 56624-93-2
ethoxycarbonyl-2 methyl-2 dioxolanne-1,3

Guidance literature:: With ethylene glycol; benzenesulfonic acid; benzene; Entfernen des entstehenden Wassers;

Reference yield:

: 56624-93-2
ethoxycarbonyl-2 methyl-2 dioxolanne-1,3

: 129435-70-7
(E)-3-<2,2-(ethylenedioxy)-propylidene>-1-phenylpyrrolidin-2-one

Guidance literature:: Multi-step reaction with 4 steps

1: 1) LDA / 1) THF, -78 deg C, 10 min, 2) THF, 30 min

2: 64 percent / NaBH₄ / methanol / 1 h / 0 °C

3: 76 percent / NEt₃ / CH₂Cl₂ / Ambient temperature

4: DBU / benzene / Heating

With sodium tetrahydroborate; 1,8-diazabicyclo[5.4.0]undec-7-ene; triethylamine; lithium diisopropyl amide; In methanol; dichloromethane; benzene;
DOI:10.1248/cpb.38.393