Platinate(1-),trichloro[(sulfinyl-kS)bis[methane]]-, potassium (1:1), (SP-4-2)-

Base Information

• Chemical Name: Platinate(1-),trichloro[(sulfinyl-kS)bis[methane]]-, potassium (1:1), (SP-4-2)-
• CAS No.: 31168-86-2
• Molecular Formula: C2H6 Cl3 O Pt S . K
• Molecular Weight: 418.672
• Mol file: 31168-86-2.mol

Synonyms:Platinate(1-),trichloro[(sulfinyl-kS)bis[methane]]-, potassium, (SP-4-2)- (9CI); Platinate(1-),trichloro[sulfinylbis[methane]-S]-, potassium, (SP-4-2)-; NSC 175278; Potassiumtrichloro(dimethyl sulfoxide)platinate; Potassium trichloro(dimethylsulfoxide)platinate(1-); Potassium trichloro(methyl sulfoxide)platinate(1-)

Chemical Property of Platinate(1-),trichloro[(sulfinyl-kS)bis[methane]]-, potassium (1:1), (SP-4-2)-

Chemical Property:

Purity/Quality:

85.0-99.8% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Platinate(1-),trichloro[(sulfinyl-kS)bis[methane]]-, potassium (1:1), (SP-4-2)-

There total 1 articles about Platinate(1-),trichloro[(sulfinyl-kS)bis[methane]]-, potassium (1:1), (SP-4-2)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

potassium tetrachloroplatinate(II) (10025-99-7) + dimethyl sulfoxide (67-68-5,8070-53-9) → cis-dichlorobis(dimethylsulfoxide)platinum(II) (75992-73-3,25794-47-2,30729-25-0,15274-33-6,22840-91-1,14568-13-9) + potassium trichloro(dimethylsulfoxide)platinate(II) (31168-86-2)

Guidance literature:

In water; addn. of org. ligand to aq. soln. of Pt-complex, reaction mixt. held at 90°C for 15-20 min; cooling (20°C); filtration from pptd. cis-Pt-complex after 30 min., not isolated from soln.;

Reference yield: 71.0%

potassium trichloro(dimethylsulfoxide)platinate(II) (31168-86-2) + curcumin (98885-93-9,115851-80-4,147556-16-9) → C23H25ClO7PtS

Guidance literature:

With potassium hydroxide; In ethanol; water; at 20 ℃; for 36h;

DOI:10.1016/j.jinorgbio.2019.110749

Reference yield: 67.0%

1-[10-(3,5-di-tert-butyl-phenoxy)-decyl]-[4,4']bipyridinyl-1-ium; chloride + potassium trichloro(dimethylsulfoxide)platinate(II) (31168-86-2) → PtCl2((CH3)2SO)C5H4NC5H4N(CH2)10OC6H3(C(CH3)3)2(1+)*PtCl3(CH3)2SO(1-)=C38H61Cl5N2O3Pt2S2 (918972-57-3,918795-55-8)

Guidance literature:

In water; addn. of aq. soln. of C5H4NC5H4N(CH2)10OC6H3(t-Bu)2Cl to aq. soln. of KPtCl3(dmso) at 0 °C, stiring for 3 min.; filtration, washing with water, drying under reduced pressure, obtained as a mixt. of isomers trans/cis 6:1;

DOI:10.1039/b610087b

upstream raw materials:

potassium tetrachloroplatinate(II)

dimethyl sulfoxide

Downstream raw materials:

trans-{Pt(dimethyl sulfoxide)(ammonia)Cl2}

cis-dichloro(dimethyl sulfoxide)(PhCH₂CN)platinum(II)

(Cl((CH₃)2SO)Pt(C₂H₃NOF))2

PtCl₂((CH₃)2SO)C₅H₄NC₅H₄N(CH₂)10OC₆H₃(C(CH₃)3)2⁽¹⁺⁾*PtCl₃(CH₃)2SO^(1-)=C₃₈H₆₁Cl₅N₂O₃Pt₂S₂