1-Iodo-1-cycloheptene

Base Information

• Chemical Name: 1-Iodo-1-cycloheptene
• CAS No.: 49565-03-9
• Molecular Formula: C7H11I
• Molecular Weight: 222.069
• Mol file: 49565-03-9.mol

Synonyms:Jod-cyclohepten;1-Jodcyclohepten;1-Iodo-1-cycloheptene;1-iodocyclohept-1-ene;(E)-1-iodocyclohept-1-ene;1-Iod-1-cyclohepten;1-iodocycloheptene;2-Iodocycloheptene;

Chemical Property of 1-Iodo-1-cycloheptene

Chemical Property:

• PSA: 0.00000
• LogP: 3.26940

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-Iodo-1-cycloheptene

There total 8 articles about 1-Iodo-1-cycloheptene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

cyclohept-1-en-1-yl trifluoromethanesulfonate (28075-51-6) → (E)-1-iodocyclohept-1-ene (49565-03-9)

Guidance literature:

With (η6-1,3,5-cyclooctatriene)(η4-1,5-cyclooctadiene)ruthenium(0); lithium iodide; In tetrahydrofuran; at 60 ℃; for 3h; Inert atmosphere;

DOI:10.1039/b907761h

Reference yield: 71.0%

1-trimethylsilylcycloheptene (61892-24-8) → (E)-1-iodocyclohept-1-ene (49565-03-9)

Guidance literature:

With iodine; In dichloromethane; at 25 ℃; for 3h;

DOI:10.1021/jo00175a032

Reference yield: 49.0%

1-chlorocycloheptene (13294-30-9) → (E)-1-iodocyclohept-1-ene (49565-03-9)

Guidance literature:

With bis(1,5-cyclooctadiene)nickel ⁽⁰⁾; sodium iodide; In N,N-dimethyl-formamide; Heating;

DOI:10.1080/00397919408011726

upstream raw materials:

1-chlorocycloheptene

1-bromocycloheptene

(cyclohepten-1-yl)diethylphosphate

1-trimethylsilylcycloheptene

Downstream raw materials:

Cycloheptene

3-methoxy-1-cycloheptene

bicyclo[3.2.0]hept-6-ene

1-methoxycycloheptene