1-Chloro-1-cycloheptene

Base Information

• Chemical Name: 1-Chloro-1-cycloheptene
• CAS No.: 13294-30-9
• Molecular Formula: C7H11Cl
• Molecular Weight: 130.617
• Hs Code.: 2903890090
• Mol file: 13294-30-9.mol

Synonyms:1-cycloheptenyl chloride;1-Chloro-1-cycloheptene;1-Chlor-cyclohepten-1;Cycloheptenylchlorid;1-Chlorcyclohepten;Cycloheptene,1-chloro;1-chloro-cycloheptene;

Chemical Property of 1-Chloro-1-cycloheptene

Chemical Property:

• Boiling Point: 58-59 °C(Press: 12 Torr)
• PSA: 0.00000
• Density: 1.0276 g/cm3
• LogP: 3.07320

Purity/Quality:

98%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1-Chloro-1-cycloheptene

There total 10 articles about 1-Chloro-1-cycloheptene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

cyclohept-1-en-1-yl trifluoromethanesulfonate (28075-51-6) → 1-chlorocycloheptene (13294-30-9)

Guidance literature:

With tris(2,4-pentanedionato)ruthenium(III); butyl magnesium bromide; lithium chloride; In tetrahydrofuran; at 60 ℃; for 3h; Inert atmosphere;

DOI:10.1039/b907761h

Reference yield: 78.0%

cycloheptanone (502-42-1) → 1-chlorocycloheptene (13294-30-9)

Guidance literature:

With phosphorus pentachloride; trichlorophosphate; at 0 ℃; for 20h;

Reference yield:

(E)-1-iodocyclohept-1-ene (49565-03-9) → Cycloheptene (628-92-2,45509-99-7) + 1-chlorocycloheptene (13294-30-9) + bicyclo[3.2.0]hept-6-ene (4927-03-1)

Guidance literature:

In dichloromethane; for 10h; Irradiation;

DOI:10.1021/ja00361a028

upstream raw materials:

cycloheptanone

(iodomethylene)cyclohexane

(E)-1-iodocyclohept-1-ene

(1R,2R)-1-Bromo-2-chloro-cycloheptane

Downstream raw materials:

1-(2-methylphenyl)cycloheptene

1-t-Butoxycyclohepten

1-bromocycloheptene

(E)-1-iodocyclohept-1-ene