S-3-iodo-2,2'-bis(MethoxyMethoxy)1,1'-Binaphthalene

Base Information

Chemical Name:S-3-iodo-2,2'-bis(MethoxyMethoxy)1,1'-Binaphthalene
CAS No.:497826-57-0
Molecular Formula:C24H21IO4
Molecular Weight:500.32600
Hs Code.:
Mol file:497826-57-0.mol

Synonyms:3-iodo-2,2'-bis(methoxymethyl)-1,1'-bi-2-naphthol;(S)-3-Iodo-2,2'-bis(methoxymethoxy)-1,1'-binaphthalene;

Suppliers and Price of S-3-iodo-2,2'-bis(MethoxyMethoxy)1,1'-Binaphthalene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of S-3-iodo-2,2'-bis(MethoxyMethoxy)1,1'-Binaphthalene

Chemical Property:

PSA：36.92000
LogP:6.23000

Purity/Quality:: >95%,>98%e.e. ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of S-3-iodo-2,2'-bis(MethoxyMethoxy)1,1'-Binaphthalene

There total 1 articles about S-3-iodo-2,2'-bis(MethoxyMethoxy)1,1'-Binaphthalene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 173831-50-0
rac-2,2'-bis-(methoxymethoxy)-1,1'-binaphthalene

: 1202022-70-5,389125-79-5,497826-57-0
(S)-3-iodo-2,2'-bis(methoxymethyl)-1,1'-bi-2-naphthol

Guidance literature:: With n-butyllithium; iodine; In tetrahydrofuran;
DOI:10.1016/j.molcata.2015.01.007

Reference yield: 91.8%

: 1202022-70-5,389125-79-5,497826-57-0
(S)-3-iodo-2,2'-bis(methoxymethyl)-1,1'-bi-2-naphthol

: 536-74-3
phenylacetylene

: C₃₂H₂₆O₄

Guidance literature:: With copper(l) iodide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; triethylamine; In acetonitrile; at 80 ℃; for 3h;
DOI:10.1021/acs.joc.8b02353

Reference yield:

: 1202022-70-5,389125-79-5,497826-57-0
(S)-3-iodo-2,2'-bis(methoxymethyl)-1,1'-bi-2-naphthol

: 536-74-3
phenylacetylene

: C₂₈H₁₈O₂

Guidance literature:: Multi-step reaction with 2 steps

1: triethylamine; copper(l) iodide; tetrakis(triphenylphosphine) palladium⁽⁰⁾ / acetonitrile / 3 h / 80 °C

2: hydrogenchloride / ethanol / 72 h / 80 °C

With hydrogenchloride; copper(l) iodide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; triethylamine; In ethanol; acetonitrile;
DOI:10.1021/acs.joc.8b02353