1-Hexanol, 5-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-2-ethyl-

Base Information

Chemical Name:1-Hexanol, 5-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-2-ethyl-
CAS No.:498572-79-5
Molecular Formula:C24H36O2Si
Molecular Weight:384.634
Hs Code.:
DSSTox Substance ID:DTXSID30461463

Synonyms:498572-79-5;1-Hexanol, 5-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-2-ethyl-;DTXSID30461463;5-(t-butyldi-phenylsilyloxy)-2-ethyl-1-hexanol

Suppliers and Price of 1-Hexanol, 5-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-2-ethyl-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemical Property of 1-Hexanol, 5-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-2-ethyl-

Chemical Property:

PSA：29.46000
LogP:4.75020
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:10
Exact Mass:384.248456921
Heavy Atom Count:27
Complexity:387

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCC(CCC(C)O[Si](C1=CC=CC=C1)(C2=CC=CC=C2)C(C)(C)C)CO

Technology Process of 1-Hexanol, 5-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-2-ethyl-

There total 4 articles about 1-Hexanol, 5-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-2-ethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 498572-78-4
1-(tert-butyldimethylsilyloxy)-2-ethyl-5-(tert-butyldiphenylsilyloxy)hexane

: 498572-79-5
5-(tert-butyldiphenylsilyloxy)-2-ethyl-hexane-1-ol

Guidance literature:: With pyridinium p-toluenesulfonate; In ethanol; at 20 ℃; for 66h;
DOI:10.1007/s007060200084

Reference yield:

: 58374-34-8
2-ethyl-hexane-1,5-diol

: 498572-79-5
5-(tert-butyldiphenylsilyloxy)-2-ethyl-hexane-1-ol

Guidance literature:: Multi-step reaction with 3 steps

1: 68 percent / imidazole / dimethylformamide / 3 h / 20 °C

2: 88 percent / imidazole; 4-dimethylaminopyridine / CH₂Cl₂ / 17 h / 20 °C

3: 76 percent / pyridinium p-toluenesulfonate / ethanol / 66 h / 20 °C

With 1H-imidazole; dmap; pyridinium p-toluenesulfonate; In ethanol; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1007/s007060200084

Reference yield:

: 35650-55-6,553638-75-8
2-ethyl-5-oxo-hexanal

: 498572-79-5
5-(tert-butyldiphenylsilyloxy)-2-ethyl-hexane-1-ol

Guidance literature:: Multi-step reaction with 4 steps

1: 77 percent / NaBH₄ / ethanol / 2 h / 20 °C

2: 68 percent / imidazole / dimethylformamide / 3 h / 20 °C

3: 88 percent / imidazole; 4-dimethylaminopyridine / CH₂Cl₂ / 17 h / 20 °C

4: 76 percent / pyridinium p-toluenesulfonate / ethanol / 66 h / 20 °C

With 1H-imidazole; dmap; sodium tetrahydroborate; pyridinium p-toluenesulfonate; In ethanol; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1007/s007060200084