1,1'-Biphenyl, 4-bromo-4'-(1,1-dimethylethoxy)-

Base Information

Chemical Name:1,1'-Biphenyl, 4-bromo-4'-(1,1-dimethylethoxy)-
CAS No.:498579-54-7
Molecular Formula:C16H17BrO
Molecular Weight:305.214
Hs Code.:
DSSTox Substance ID:DTXSID30431525
Wikidata:Q82245436

Synonyms:1,1'-Biphenyl, 4-bromo-4'-(1,1-dimethylethoxy)-;498579-54-7;DTXSID30431525

Suppliers and Price of 1,1'-Biphenyl, 4-bromo-4'-(1,1-dimethylethoxy)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1,1'-Biphenyl, 4-bromo-4'-(1,1-dimethylethoxy)-

Chemical Property:

XLogP3:6
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:3
Exact Mass:304.04628
Heavy Atom Count:18
Complexity:242

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC(C)(C)OC1=CC=C(C=C1)C2=CC=C(C=C2)Br

Technology Process of 1,1'-Biphenyl, 4-bromo-4'-(1,1-dimethylethoxy)-

There total 1 articles about 1,1'-Biphenyl, 4-bromo-4'-(1,1-dimethylethoxy)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

: 29558-77-8
4-bromo-4'-hydroxybiphenyl

: 115-11-7,15220-85-6
isobutene

: 498579-54-7
4-bromo-4'-tert-butoxybiphenyl

Guidance literature:: With sulfuric acid; In chloroform; at 20 ℃;
DOI:10.1021/ja049325w

Reference yield: 78.0%

: 498579-54-7
4-bromo-4'-tert-butoxybiphenyl

: 808142-60-1
4-(2-octyl-dodecyloxy)biphenyl-4'-boronic acid

: 808142-61-2
4'''-tert-butoxy-4-(2-octyl-dodecyloxy)-[1,4';1',1'';4'',1''']quaterphenyl

Guidance literature:: With tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate; In ethanol; toluene; Heating;
DOI:10.1021/ja049325w

Reference yield:

: 498579-54-7
4-bromo-4'-tert-butoxybiphenyl

: 808142-62-3
4'''-(2-octyl-dodecyloxy)-[1,4';1',1'';4'',1''']quaterphenyl-4-ol

Guidance literature:: Multi-step reaction with 2 steps

1: 78 percent / aq. Na₂CO₃; Pd(PPh₃)4 / toluene; ethanol / Heating

2: 93 percent / trifluoroacetic acid / CH₂Cl₂ / 4 h / 20 °C

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate; trifluoroacetic acid; In ethanol; dichloromethane; toluene; 1: Suzuki coupling;
DOI:10.1021/ja049325w