Bis(trichloromethyl)mercury

Base Information

• Chemical Name: Bis(trichloromethyl)mercury
• CAS No.: 6795-81-9
• Molecular Formula: C2Cl6 Hg
• Molecular Weight: 437.33
• Hs Code.: 2931900090
• European Community (EC) Number: 229-867-5
• NSC Number: 308783
• DSSTox Substance ID: DTXSID90218157
• Mol file: 6795-81-9.mol

Synonyms:Bis(trichloromethyl)mercury;6795-81-9;EINECS 229-867-5;NSC308783;C2Cl6Hg;C2-Cl6-Hg;bis-(Trichloromethyl)mercury;C(Cl)(Cl)Cl.ClC(Cl)Cl;DTXSID90218157;AKOS024430749;NSC 308783;NSC-308783

Chemical Property of Bis(trichloromethyl)mercury

Chemical Property:

• Melting Point: 140-142 °C
• PSA: 0.00000
• LogP: 4.56410
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 437.780810
• Heavy Atom Count: 9
• Complexity: 76.2

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C(Cl)(Cl)(Cl)[Hg]C(Cl)(Cl)Cl

Technology Process of Bis(trichloromethyl)mercury

There total 2 articles about Bis(trichloromethyl)mercury which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

chloroform (67-66-3,8013-54-5) + Hg(3,3',5,5'-tetramethyl-4,4'-dibutyldipyrrolylmethene-2,2'(-1H))2 (481711-40-4) → (CCl3)Hg(3,3',5,5'-tetramethyl-4,4'-dibutyl-2,2'-dipyrrolylmethene-H) + bis-trichloromethyl-mercury (6795-81-9)

Guidance literature:

In chloroform; in CHCl3 soln. at 318.15 K for 10 d; detd. by UV spectra studies;

DOI:10.1007/s11176-005-0152-y

Reference yield:

→ bis-trichloromethyl-mercury (6795-81-9)

Guidance literature:

Cl3CLi, HgCl2, in THF/Ae./PAe. (4:1:1), unter N2 bei -108grad;

Reference yield: 90.0%

trimethylstannane (1631-73-8) + bis-trichloromethyl-mercury (6795-81-9) → trichloromethyl-trimethyl tin (13340-12-0)

Guidance literature:

In benzene; at 0°C;;

upstream raw materials:

chloroform

Hg(3,3',5,5'-tetramethyl-4,4'-dibutyldipyrrolylmethene-2,2'(-1H))2

Downstream raw materials:

trichloromethyl-trimethyl tin

Rh(CO)(P(C₆H₅)3)2Cl₃

nitrosyl(trichloromethyl)(trichloromethylmercurio)bis(triphenylphosphine)rhodium