[S,(+)]-1,4-Dimethyl-4-[(R)-1-methyl-2-methylenecyclopentyl]cyclohexene

Base Information Edit

Chemical Name:[S,(+)]-1,4-Dimethyl-4-[(R)-1-methyl-2-methylenecyclopentyl]cyclohexene
CAS No.:24493-43-4
Molecular Formula:C15H24
Molecular Weight:204.356
Hs Code.:2902199090
Mol file:24493-43-4.mol

Synonyms:Cyclohexene,1,4-dimethyl-4-(1-methyl-2-methylenecyclopentyl)-, [R-(R*,S*)]-; (+)-b-Bazzanene; Bazzanene; Bazzanene,(+)-; b-Bazzanene

Suppliers and Price of [S,(+)]-1,4-Dimethyl-4-[(R)-1-methyl-2-methylenecyclopentyl]cyclohexene

Supply Marketing:Edit

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Total 1 raw suppliers

Chemical Property of [S,(+)]-1,4-Dimethyl-4-[(R)-1-methyl-2-methylenecyclopentyl]cyclohexene Edit

Chemical Property:

Vapor Pressure:0.0244mmHg at 25°C
Boiling Point:256.7°C at 760 mmHg
Flash Point:99.2°C
PSA：0.00000
Density:0.89g/cm³
LogP:4.86930

Purity/Quality:: 98% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of [S,(+)]-1,4-Dimethyl-4-[(R)-1-methyl-2-methylenecyclopentyl]cyclohexene

There total 21 articles about [S,(+)]-1,4-Dimethyl-4-[(R)-1-methyl-2-methylenecyclopentyl]cyclohexene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 104762-26-7
(2-methyl-1-cyclopentenyl)methyl 4-methyl-3-cyclohexene-1-carboxylate

: 24493-43-4,28624-60-4,61505-17-7,76231-80-6,80784-16-3
(+/-)-bazzanene

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) LDA

2: LiAlH₄ / diethyl ether / 12 h / 25 °C

3: 1.) n-BuLi, N,N,N',N'-tetramethylethylenediamine / 1.) dimethoxyethane, hexane, 0 deg C, 5 min, 2.) dimethoxyethane, hexane, RT, 1 h

4: Li, t-BuOH, ethylamine / 2 h / 0 °C

With lithium aluminium tetrahydride; n-butyllithium; N,N,N,N,-tetramethylethylenediamine; lithium; ethylamine; tert-butyl alcohol; lithium diisopropyl amide; In diethyl ether;
DOI:10.1021/jo00373a032

Reference yield:

: 16695-95-7
(4'-methylcyclohex-3'-ene-1-'-yl)carbonyl chloride

: 24493-43-4,28624-60-4,61505-17-7,76231-80-6,80784-16-3
(+/-)-bazzanene

Guidance literature:: Multi-step reaction with 5 steps

1: 81 percent / pyridine / 12 h / Ambient temperature

2: 1.) LDA

3: LiAlH₄ / diethyl ether / 12 h / 25 °C

4: 1.) n-BuLi, N,N,N',N'-tetramethylethylenediamine / 1.) dimethoxyethane, hexane, 0 deg C, 5 min, 2.) dimethoxyethane, hexane, RT, 1 h

5: Li, t-BuOH, ethylamine / 2 h / 0 °C

With pyridine; lithium aluminium tetrahydride; n-butyllithium; N,N,N,N,-tetramethylethylenediamine; lithium; ethylamine; tert-butyl alcohol; lithium diisopropyl amide; In diethyl ether;
DOI:10.1021/jo00373a032

Reference yield:

: C₁₈H₃₀O₂Si

: 24493-43-4,28624-60-4,61505-17-7,76231-80-6,80784-16-3
(+/-)-bazzanene

Guidance literature:: Multi-step reaction with 3 steps

1: LiAlH₄ / diethyl ether / 12 h / 25 °C

2: 1.) n-BuLi, N,N,N',N'-tetramethylethylenediamine / 1.) dimethoxyethane, hexane, 0 deg C, 5 min, 2.) dimethoxyethane, hexane, RT, 1 h

3: Li, t-BuOH, ethylamine / 2 h / 0 °C

With lithium aluminium tetrahydride; n-butyllithium; N,N,N,N,-tetramethylethylenediamine; lithium; ethylamine; tert-butyl alcohol; In diethyl ether;
DOI:10.1021/jo00373a032