Tris(4-chlorophenyl)(sulfanylidene)-lambda~5~-phosphane

Base Information

• Chemical Name: Tris(4-chlorophenyl)(sulfanylidene)-lambda~5~-phosphane
• CAS No.: 5032-62-2
• Molecular Formula: C18H12Cl3PS
• Molecular Weight: 397.692
• DSSTox Substance ID: DTXSID30507274
• Nikkaji Number: J465.438B
• Wikidata: Q82363405
• Mol file: 5032-62-2.mol

Synonyms:5032-62-2;SCHEMBL9756552;Tris(4-chlorophenyl)(sulfanylidene)-lambda~5~-phosphane;DTXSID30507274

Chemical Property of Tris(4-chlorophenyl)(sulfanylidene)-lambda~5~-phosphane

Chemical Property:

• XLogP3: 7.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 395.946292
• Heavy Atom Count: 23
• Complexity: 358

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C1=CC(=CC=C1P(=S)(C2=CC=C(C=C2)Cl)C3=CC=C(C=C3)Cl)Cl

Technology Process of Tris(4-chlorophenyl)(sulfanylidene)-lambda~5~-phosphane

There total 10 articles about Tris(4-chlorophenyl)(sulfanylidene)-lambda~5~-phosphane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

diphenyl trisulfide (20057-88-9) + tri(4-chlorophenyl)phosphine (1159-54-2) → tris-p-chlorophenylphosphine sulphide (5032-62-2) + diphenyldisulfane (882-33-7)

Guidance literature:

In ⁽²⁾H₈-toluene; toluene; at 25 ℃; Rate constant;

Reference yield:

N-phenyl-1,2,4-dithiazolidine-3,5-dione (21597-12-6) + tri(4-chlorophenyl)phosphine (1159-54-2) → tris-p-chlorophenylphosphine sulphide (5032-62-2) + phenyl isocyanate (103-71-9)

Guidance literature:

In acetonitrile; at 25 ℃; Concentration; Solvent; Kinetics;

DOI:10.1002/poc.3131

Reference yield:

tri(4-chlorophenyl)phosphine (1159-54-2) → tris-p-chlorophenylphosphine sulphide (5032-62-2)

Guidance literature:

With 3-amino-1,2,4-dithiazole-5-thione; In acetonitrile; at 25 ℃; Further Variations:; Reagents; Kinetics;

DOI:10.1039/b616298c

upstream raw materials:

chlorobenzene

toluene

benzene

diphenyl trisulfide

Downstream raw materials:

(E)-N-methyl-1-(4-nitrophenyl)methanimine

tris(p-chlorophenyl)phosphine oxide

4-nitrobenzaldehdye