(E)-1-Chloro-1-hexene

Base Information

• Chemical Name: (E)-1-Chloro-1-hexene
• CAS No.: 50586-19-1
• Molecular Formula: C6H11Cl
• Molecular Weight: 118.60500
• Hs Code.: 2903299090
• Mol file: 50586-19-1.mol

Synonyms:1t-chloro-hex-1-ene;(E)-1-Chlorhexen-1;1t-Chlor-hex-1-en;(E)-1-Chlor-1-hexen;trans-1-Chlor-1-hexen;trans-1-Chlor-hexen-(1);

Chemical Property of (E)-1-Chloro-1-hexene

Chemical Property:

• Refractive Index: 1.4270
• Boiling Point: 134.88°C (estimate)
• PSA: 0.00000
• Density: 0.9241 (estimate)
• LogP: 2.92910

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (E)-1-Chloro-1-hexene

There total 13 articles about (E)-1-Chloro-1-hexene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

trans-1,2-dichloroethylene (156-60-5,43695-79-0) + butyl magnesium bromide (693-04-9) → (E)-1-chloro-1-hexene (50586-19-1)

Guidance literature:

With tetrakis(triphenylphosphine)nickel⁽⁰⁾; In diethyl ether; benzene; for 2.5h; Ambient temperature;

Reference yield:

cis-1,2-Dichloroethylene (156-59-2,43695-79-0) → (Z)-1-chloro-hex-1-ene (50586-18-0) + (E)-1-chloro-1-hexene (50586-19-1)

Guidance literature:

In dimethyl sulfoxide; for 21h; Yield given. Yields of byproduct given; Irradiation;

DOI:10.1021/ja00219a030

Reference yield:

trans-1,2-dichloroethylene (156-60-5,43695-79-0) → (Z)-1-chloro-hex-1-ene (50586-18-0) + (E)-1-chloro-1-hexene (50586-19-1)

Guidance literature:

In dimethyl sulfoxide; for 20h; Yield given. Yields of byproduct given; Irradiation;

DOI:10.1021/ja00219a030

upstream raw materials:

n-butyl magnesium bromide

trans-1,2-dichloroethylene

1,1-dichloro-n-hexane

(Z)-hex-1-enyl(trimethyl)silane

Downstream raw materials:

(E)-hept-2-enenitrile