Butylmagnesium chloride

Base Information

• Chemical Name: Butylmagnesium chloride
• CAS No.: 693-04-9
• Molecular Formula: C4H9ClMg
• Molecular Weight: 116.873
• Hs Code.: 29319090
• European Community (EC) Number: 211-739-5
• DSSTox Substance ID: DTXSID0074924
• Mol file: 693-04-9.mol

Synonyms:Butylmagnesiumchloride (6CI);Butylchloromagnesium;Butylmagnesiumm chloride;n-Butylmagnesium chloride;

Chemical Property of Butylmagnesium chloride

Chemical Property:

• Appearance/Colour: green-brown to brown solution
• Melting Point: -17°C
• Boiling Point: 66 °C
• Flash Point: 115 °F
• PSA: 0.00000
• Density: 0.962 g/mL at 25 °C
• LogP: 2.44360
• Storage Temp.: 2-8°C
• Sensitive.: Air & Moisture Sensitive
• Water Solubility.: reacts
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 1
• Exact Mass: 116.0243197
• Heavy Atom Count: 6
• Complexity: 11.5

Purity/Quality:

99% ^*data from raw suppliers

ButylmagnesiumChloride ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F,C
• Hazard Codes: C,F,F+
• Statements: 12-14/15-19-22-34-67-65-63-48/20-11-15-14-10-40-37
• Safety Statements: 7-9-16-26-29-33-36/37/39-43-45-62-46

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCC[CH2-].[Mg+2].[Cl-]
• Uses: n-Butylmagnesium chloride is used in organic synthesis, pharmaceuticals, agrochemicals and dyestuffs. Butylmagnesium chloride (BuMgCl) is a Grignard reagent that can be used:To prevent the formation of passivating surface films on Mg electrodes.For the synthesis of lithium tributylmagnesate complex (n-Bu3MgLi) by reacting with n-BuLi.

Technology Process of Butylmagnesium chloride

There total 9 articles about Butylmagnesium chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

n-Butyl chloride (109-69-3) → butyl magnesium bromide (693-04-9)

Guidance literature:

With magnesium; In tetrahydrofuran-d8; at 80 ℃; under 5171.62 Torr; Inert atmosphere; Flow reactor;

DOI:10.3762/bjoc.16.115

Reference yield:

triethylaluminum (97-93-8) + n-butyl-ethylmagnesium (62202-86-2) → hydridomagnesium chloride (14989-29-8) + (AlEt3)2*MgEt2 + butyl magnesium bromide (693-04-9) + ethylmagnesium chloride (2386-64-3) + magnesium chloride (7786-30-3)

Guidance literature:

In 2-Methylpentane; for 4383h; Reactivity;

Reference yield:

butyltriethoxy silane (4781-99-1) + EtOMgCl → tetraethoxy orthosilicate (78-10-4) + butyl magnesium bromide (693-04-9)

Guidance literature:

In tert-butyl methyl ether; toluene; at 20 ℃; Solvent; Equilibrium constant; Inert atmosphere;

DOI:10.1080/10426501003713106

upstream raw materials:

n-Butyl chloride

9,10-dihydro-9,10-anthracendiyl-tris(THF)magnesium

diethyl ether

triethylaluminum

Downstream raw materials:

2-pentylfuran

9-(4-butylphenyl)phenanthrene

4-(1-acetoxy-cyclohexyl)-but-3-yn-2-one

3-methyl-1-heptene

Refernces

Formation and structural characterization of a five-membered zirconacycloallenoid

10.1039/c3dt51497h

The study focuses on the formation and structural characterization of a five-membered zirconacycloallenoid, a type of metallocene complex, through the reaction of a conjugated enyne with in situ generated zirconocene. The resulting compound was thoroughly analyzed using X-ray diffraction, revealing its unique structure and bonding characteristics. The research also explored the compound's reactivity, demonstrating its distinct behavior in reactions with additional zirconocene and acetonitrile, leading to the formation of different complexes. This work not only provides detailed insights into the structure and properties of metallacycloallenoid complexes but also uncovers new chemical reactions and potential applications in organometallic chemistry.