Benzenediazonium, 4-methyl-, acetate

Base Information

• Chemical Name: Benzenediazonium, 4-methyl-, acetate
• CAS No.: 50715-67-8
• Molecular Formula: C₂H₃O₂*C₇H₇N₂
• Molecular Weight: 178.191
• DSSTox Substance ID: DTXSID40484527
• Mol file: 50715-67-8.mol

Synonyms:Benzenediazonium, 4-methyl-, acetate;50715-67-8;DTXSID40484527

Chemical Property of Benzenediazonium, 4-methyl-, acetate

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 178.074227566
• Heavy Atom Count: 13
• Complexity: 151

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=CC=C(C=C1)[N+]#N.CC(=O)[O-]

Technology Process of Benzenediazonium, 4-methyl-, acetate

There total 1 articles about Benzenediazonium, 4-methyl-, acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

p-toluidine (106-49-0,12221-03-3) + acetic acid (64-19-7,77671-22-8) → 4-methylphenyldiazonium acetate (50715-67-8)

Guidance literature:

With n-Butyl nitrite;

DOI:10.1002/hlca.201200042

Reference yield: 60.0%

dichloro(4-methylphenyl)stibine (87856-09-5) + 4-methylphenyldiazonium acetate (50715-67-8) → (4-CH3C6H4)2Sb(O)OH (5430-43-3) + 4-CH3C6H4Sb(O2CCH3)2*{4-CH3C6H4N2}O2CCH3

Guidance literature:

In acetone; ratio of 4-CH3C6H4SbCl2 and (4-CH3C6H4N2)O2CCH3 = 1:2; mixture was boiled briefly to evolve N2; (4-CH3C6H4)2Sb(O)OH is in filtrate;

Reference yield: 20.0%

dichloro(4-methylphenyl)stibine (87856-09-5) + 4-methylphenyldiazonium acetate (50715-67-8) → (4-CH3C6H4)2Sb(O)OH (5430-43-3) + (CH3C6H4)Sb(O2CCH3)2*{CH3C6H4N2}(1+)*O2CCH3(1-)=(CH3C6H4)Sb(O2CCH3)2*{CH3C6H4N2}O2CCH3

Guidance literature:

In acetone;

upstream raw materials:

p-toluidine

acetic acid

Downstream raw materials:

4-methyl-2-(3-phenyl-5-p-tolyl-formazan-1-yl)-selenazole-5-carboxylic acid ethyl ester

1-(4,5-diphenyl-selenazol-2-yl)-3-phenyl-5-p-tolyl-formazan

3-p-tolyldiazenyl-2-p-tolyloxy-benzothiazolium; acetate

(4-CH₃C₆H₄)2Sb(O)OH