Silane, (2,2-diphenylethenyl)trimethyl-

Base Information

• Chemical Name: Silane, (2,2-diphenylethenyl)trimethyl-
• CAS No.: 51318-07-1
• Molecular Formula: C17H20Si
• Molecular Weight: 252.431
• DSSTox Substance ID: DTXSID20474168
• Nikkaji Number: J1.507.984C
• Mol file: 51318-07-1.mol

Synonyms:Silane, (2,2-diphenylethenyl)trimethyl-;51318-07-1;DTXSID20474168;1,1-diphenyl-2-trimethylsilyl ethylene

Chemical Property of Silane, (2,2-diphenylethenyl)trimethyl-

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 252.133427172
• Heavy Atom Count: 18
• Complexity: 253

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Si](C)(C)C=C(C1=CC=CC=C1)C2=CC=CC=C2

Technology Process of Silane, (2,2-diphenylethenyl)trimethyl-

There total 35 articles about Silane, (2,2-diphenylethenyl)trimethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

benzophenone (119-61-9) → 1,1-diphenyl-2-trimethylsilylethene (51318-07-1)

Guidance literature:

In toluene; at 60 ℃;

DOI:10.1016/0040-4039(95)00579-2

Reference yield: 81.0%

benzophenone (119-61-9) + (ethoxydimethylsilyl)(trimethylsilyl)methane (17883-02-2) → 1,1-diphenyl-2-trimethylsilylethene (51318-07-1)

Guidance literature:

(ethoxydimethylsilyl)(trimethylsilyl)methane; With tert.-butyl lithium; In pentane; at 20 ℃; for 2h;

benzophenone; In pentane; at -78 - 20 ℃;

DOI:10.1016/S0022-328X(00)00803-2

Reference yield: 79.0%

2,2-diphenyl-1,3-dithiolane (6317-10-8) + (trimethylsilyl)methylmagnesium chloride (13170-43-9) → 1,1-diphenyl-2-trimethylsilylethene (51318-07-1)

Guidance literature:

With bis(triphenylphosphine)nickel(II) chloride; In diethyl ether; benzene; for 16h; Heating;

upstream raw materials:

n-butyllithium

1-chloro-2,2-diphenyl-1-(trimethylsilyl)ethene

benzophenone

bis(trimethylsilyl)methane

Downstream raw materials:

(E)-ethyl 6,6-diphenylhexa-2,5-dienoate