1-Bromomethyl-4-methylsulfinylbenzene

Base Information

Chemical Name:1-Bromomethyl-4-methylsulfinylbenzene
CAS No.:51927-46-9
Molecular Formula:C8H9BrOS
Molecular Weight:233.129
Hs Code.:
DSSTox Substance ID:DTXSID40475071
Nikkaji Number:J2.542.981H
Mol file:51927-46-9.mol

Synonyms:51927-46-9;Benzene, 1-(bromomethyl)-4-(methylsulfinyl)-;1-bromomethyl-4-methanesulfinyl-benzene;1-Bromomethyl-4-methylsulfinylbenzene;1-(bromomethyl)-4-methylsulfinylbenzene;SCHEMBL1940530;4-(Methylsulfinyl)benzyl bromide;DTXSID40475071;TWRRPMMTNQLFRF-UHFFFAOYSA-N;FT-0745134;1-(BROMOMETHYL)-4-METHANESULFINYLBENZENE

Suppliers and Price of 1-Bromomethyl-4-methylsulfinylbenzene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of 1-Bromomethyl-4-methylsulfinylbenzene

Chemical Property:

XLogP3:1.6
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:2
Exact Mass:231.95575
Heavy Atom Count:11
Complexity:141

Purity/Quality:: 98%min ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CS(=O)C1=CC=C(C=C1)CBr

Technology Process of 1-Bromomethyl-4-methylsulfinylbenzene

There total 3 articles about 1-Bromomethyl-4-methylsulfinylbenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 38185-19-2
4-(methylthio)benzyl bromide

: 51927-46-9
1-bromomethyl-4-methanesulfinylbenzene

Guidance literature:: With dihydrogen peroxide; In acetic acid; at 20 ℃; for 20h;

Reference yield: 52.0%

: 38185-19-2
4-(methylthio)benzyl bromide

: 3446-90-0
4-(methylthio)benzyl alcohol

: 51927-46-9
1-bromomethyl-4-methanesulfinylbenzene

: 3446-89-7
4-(Methylthio)benzaldehyde

Guidance literature:: With dihydrogen peroxide; at 70 ℃; for 1h;
DOI:10.1002/adsc.200700206

Reference yield:

: 3446-90-0
4-(methylthio)benzyl alcohol

: 51927-46-9
1-bromomethyl-4-methanesulfinylbenzene

Guidance literature:: Multi-step reaction with 2 steps

1: 99 percent / trimethylsilyl bromide / CHCl₃ / 1 h / 0 °C

2: 75 percent / 30percent H₂O₂ / acetic acid / 20 h / 20 °C

With trimethylsilyl bromide; dihydrogen peroxide; In chloroform; acetic acid;