Technology Process of Benzaldehyde, 3-methyl-2-(1-methylethoxy)-
There total 2 articles about Benzaldehyde, 3-methyl-2-(1-methylethoxy)- which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
potassium carbonate;
In
DMF (N,N-dimethyl-formamide);
at 20 - 45 ℃;
for 30h;
- Guidance literature:
-
Multi-step reaction with 6 steps
1.1: caesium carbonate / tetrahydrofuran; isopropyl alcohol / 48 h
1.2: 9 h
2.1: boron trifluoride diethyl etherate; (-)-diisopinocamphenylborane chloride / tetrahydrofuran / 15 h / -40 - 20 °C
2.2: 0.75 h
3.1: hydrogen / platinum(IV) oxide / 15 h / 2585.81 Torr
4.1: boron trifluoride diethyl etherate / dichloromethane / 18 h / 20 °C / Heating / reflux
4.2: pH 13
5.1: triethylamine / dichloromethane / 10 °C
6.1: lithium aluminium tetrahydride / diethyl ether / 3.5 h / 20 °C / Heating / reflux
With
lithium aluminium tetrahydride; boron trifluoride diethyl etherate; hydrogen; caesium carbonate; triethylamine; (-)-diisopinocamphenylborane chloride;
platinum(IV) oxide;
In
tetrahydrofuran; diethyl ether; dichloromethane; isopropyl alcohol;
1.1: Horner-Emmons reaction;