Cyclohexanone, 2-[(trimethylsilyl)oxy]-

Base Information

Chemical Name:Cyclohexanone, 2-[(trimethylsilyl)oxy]-
CAS No.:53638-19-0
Molecular Formula:C9H18O2Si
Molecular Weight:186.326
Hs Code.:
DSSTox Substance ID:DTXSID50464335
Nikkaji Number:J1.925.858K
Mol file:53638-19-0.mol

Synonyms:Cyclohexanone, 2-[(trimethylsilyl)oxy]-;53638-19-0;SCHEMBL3438152;DTXSID50464335;2-[(trimethylsilyl)oxy]cyclohexanone

Suppliers and Price of Cyclohexanone, 2-[(trimethylsilyl)oxy]-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Cyclohexanone, 2-[(trimethylsilyl)oxy]-

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:2
Exact Mass:186.107606347
Heavy Atom Count:12
Complexity:172

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C[Si](C)(C)OC1CCCCC1=O

Technology Process of Cyclohexanone, 2-[(trimethylsilyl)oxy]-

There total 7 articles about Cyclohexanone, 2-[(trimethylsilyl)oxy]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

: 6651-36-1
1-(Trimethylsilyloxy)cyclohexene

: 53638-19-0
2-hydroxycyclohexanone trimethylsilyl ether

Guidance literature:: 1-(Trimethylsilyloxy)cyclohexene; With potassium carbonate; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; water; at 0 ℃; for 1h;

With silica gel; In Petroleum ether; at 20 ℃; for 6h;
DOI:10.1021/ol034594x

Reference yield:

: 6651-36-1
1-(Trimethylsilyloxy)cyclohexene

: 930-68-7
cyclohexenone

: 53638-19-0
2-hydroxycyclohexanone trimethylsilyl ether

: 533-60-8
cyclohexanone-2-ol

Guidance literature:: Yield given. Multistep reaction. Yields of byproduct given;

Reference yield:

: 108-94-1,11119-77-0,9003-41-2,9075-99-4
cyclohexanone

: 53638-19-0
2-hydroxycyclohexanone trimethylsilyl ether

Guidance literature:: Multi-step reaction with 2 steps

1: LDA / tetrahydrofuran

2: MCPBA / CH₂Cl₂ / 0 °C

With 3-chloro-benzenecarboperoxoic acid; lithium diisopropyl amide; In tetrahydrofuran; dichloromethane;
DOI:10.1016/S0040-4039(01)85585-4