Silanamine, 1-(1,1-dimethylethyl)-1,1-dimethyl-N-phenyl-

Base Information

• Chemical Name: Silanamine, 1-(1,1-dimethylethyl)-1,1-dimethyl-N-phenyl-
• CAS No.: 53742-62-4
• Molecular Formula: C12H21NSi
• Molecular Weight: 207.391
• DSSTox Substance ID: DTXSID00467497
• Nikkaji Number: J46.892D
• Wikidata: Q63395237
• Mol file: 53742-62-4.mol

Synonyms:N-(tert-Butyldimethylsilyl)aniline;Silanamine, 1-(1,1-dimethylethyl)-1,1-dimethyl-N-phenyl-;53742-62-4;DTXSID00467497;UITYJPORVGLJRW-UHFFFAOYSA-N;Aniline, N-tert-butyldimethylsilyl-;1-tert-Butyl-1,1-dimethyl-N-phenylsilanamine;Benzenamine, N-[(1,1-dimethylethyl)dimethylsilyl]-;Q63395237

Chemical Property of Silanamine, 1-(1,1-dimethylethyl)-1,1-dimethyl-N-phenyl-

Chemical Property:

• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 207.144326209
• Heavy Atom Count: 14
• Complexity: 175

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CC(C)(C)[Si](C)(C)NC1=CC=CC=C1

Technology Process of Silanamine, 1-(1,1-dimethylethyl)-1,1-dimethyl-N-phenyl-

There total 6 articles about Silanamine, 1-(1,1-dimethylethyl)-1,1-dimethyl-N-phenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

tert-butyldimethylsilyl chloride (18162-48-6) + aniline (62-53-3) → anilino(tert-butyldimethyl)silane (53742-62-4)

Guidance literature:

aniline; With methyllithium; In 2-methyltetrahydrofuran; diethyl ether; at 0 ℃; Inert atmosphere;

tert-butyldimethylsilyl chloride; In 2-methyltetrahydrofuran; diethyl ether; at 0 - 20 ℃; Inert atmosphere;

DOI:10.1039/c1gc15574a

Reference yield: 84.0%

tert-butyldimethylsilyl chloride (18162-48-6) + Azobenzene (1227476-15-4) → anilino(tert-butyldimethyl)silane (53742-62-4)

Guidance literature:

With lithium; iron(III) chloride; In tetrahydrofuran; for 10h; Ambient temperature;

DOI:10.1246/cl.1987.153

Reference yield:

tert-butyldimethylsilane (29681-57-0) + aniline (62-53-3) → anilino(tert-butyldimethyl)silane (53742-62-4)

Guidance literature:

palladium on activated charcoal; In toluene; at 110 ℃;

DOI:10.1055/s-2005-872098

upstream raw materials:

tert-butyldimethylsilyl chloride

aniline

1-bromo-butane

Azobenzene

Downstream raw materials:

aniline

C₁₂H₂₀NSi

N-methylaniline hydrochloride

1-tert-butyl-N,1,1-trimethyl-N-phenylsilanamine