2,4-DIIODO-1,3,5-TRIMETHYL-BENZENE

Base Information

• Chemical Name: 2,4-DIIODO-1,3,5-TRIMETHYL-BENZENE
• CAS No.: 53779-84-3
• Molecular Formula: C9H10I2
• Molecular Weight: 371.987
• Hs Code.: 2903999090
• Mol file: 53779-84-3.mol

Synonyms:2,4-Diiodomesitylene;1,3-Diiodo-2,4,6-trimethyliodobenzene;Benzene,2,4-diiodo-1,3,5-trimethyl;2,4-Dijod-1,3,5-trimethyl-benzol;1,3-diiodo-2,4,6-trimethylbenzene;2,4-diiodo-1,3,5-trimethyl-benzene;diiodomesitylene;

Chemical Property of 2,4-DIIODO-1,3,5-TRIMETHYL-BENZENE

Chemical Property:

• Melting Point: 82-83 °C(Solv: ethanol (64-17-5))
• Boiling Point: 322.8±37.0 °C(Predicted)
• PSA: 0.00000
• Density: 2.039±0.06 g/cm3(Predicted)
• LogP: 3.82100

Purity/Quality:

95%-98% ^*data from raw suppliers

2,4-DIIODO-1,3,5-TRIMETHYL-BENZENE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2,4-DIIODO-1,3,5-TRIMETHYL-BENZENE

There total 10 articles about 2,4-DIIODO-1,3,5-TRIMETHYL-BENZENE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

1,3,5-trimethyl-benzene (108-67-8) → 2,4-diiodomesitylene (53779-84-3)

Guidance literature:

With N,N,N-trimethylbenzenemethanaminium dichloroiodate; zinc(II) chloride; In acetic acid; at 70 ℃; for 28h;

DOI:10.1246/bcsj.62.439

Reference yield: 96.0%

1,3,5-trimethyl-benzene (108-67-8) → iodomesitylene (4028-63-1) + 2,4-diiodomesitylene (53779-84-3)

Guidance literature:

With [bis(acetoxy)iodo]benzene; iodine; In ethyl acetate; at 60 ℃; for 16h;

DOI:10.1055/s-1998-1713

Reference yield: 79.0%

1,3,5-trimethyl-benzene (108-67-8) → 2,4-diiodomesitylene (53779-84-3) + 2,4,6-triiodomesitylene (19025-36-6)

Guidance literature:

With poly; iodine; In ethyl acetate; at 60 ℃; for 16h;

DOI:10.1055/s-1998-1713

upstream raw materials:

iodomesitylene

1,3,5-trimethyl-benzene

sulfur trioxide

mesitylene sulfonic acid

Downstream raw materials:

2,4,6-triiodomesitylene

1,3-diiodo-2,4,6-trimethyl-5-nitro-benzene

2,4-bis(4-bromophenylthio)-1,3,5-trimethylbenzene

Refernces

• 1、 Bai, Feng-Ying,Guan, Qing-Lin,Liu, Chun-Hong,Sun, Li-Xian,Xing, Yong-Heng,Yang, Xiao-Dong. "Polyiodine-Modified 1,3,5-Benzenetricarboxylic Acid Framework Zn(II)/Cd(II) Complexes as Highly Selective Fluorescence Sensors for Thiamine Hydrochloride, NACs, and Fe3+/Zn2+". . p. 8081 - 8098. Retrieved 2020/07/03.
• 2、 Bose, Anima,Mal, Prasenjit. "Electrophilic aryl-halogenation using N-halosuccinimides under ball-milling". . p. 2154 - 2156. Retrieved 2015/03/18.