Benzene, 1,1'-(3,3-dimethyl-1-cyclopentene-1,2-diyl)bis-

Base Information

Chemical Name:Benzene, 1,1'-(3,3-dimethyl-1-cyclopentene-1,2-diyl)bis-
CAS No.:54007-91-9
Molecular Formula:C19H20
Molecular Weight:248.368
Hs Code.:

Synonyms:Benzene,1,1'-(3,3-dimethyl-1-cyclopentene-1,2-diyl)bis;1,2-Diphenyl-5,5-dimethyl-cyclopenten(1);

Suppliers and Price of Benzene, 1,1'-(3,3-dimethyl-1-cyclopentene-1,2-diyl)bis-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Benzene, 1,1'-(3,3-dimethyl-1-cyclopentene-1,2-diyl)bis-

Chemical Property:

Boiling Point:353.9±42.0 °C(Predicted)
PSA：0.00000
Density:1.014±0.06 g/cm3(Predicted)
LogP:5.41740

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Benzene, 1,1'-(3,3-dimethyl-1-cyclopentene-1,2-diyl)bis-

There total 4 articles about Benzene, 1,1'-(3,3-dimethyl-1-cyclopentene-1,2-diyl)bis- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 62707-15-7
(5-methylhex-1-yn-1-yl)benzene

: 58109-40-3
diphenyliodonium hexafluorophosphate

: 54007-91-9
(3,3-dimethylcyclopent-1-ene-1,2-diyl)dibenzene

Guidance literature:: diphenyliodonium hexafluorophosphate; With copper(II) bis(trifluoromethanesulfonate); at 80 ℃; for 1h; Inert atmosphere; Sealed tube; Schlenk technique;

(5-methylhex-1-yn-1-yl)benzene; In 1,2-dichloro-ethane; at 60 ℃; for 12h; regioselective reaction; Inert atmosphere; Sealed tube; Schlenk technique;
DOI:10.1021/ol501655g

Reference yield: 60.0%

: 62707-15-7
(5-methylhex-1-yn-1-yl)benzene

: 66003-76-7
Diphenyliodonium triflate

: 54007-91-9
(3,3-dimethylcyclopent-1-ene-1,2-diyl)dibenzene

Guidance literature:: With 2,6-di-tert-butyl-pyridine; copper(l) chloride; In dichloromethane; at 50 ℃; for 24h; Inert atmosphere;
DOI:10.1021/ja504361y

Reference yield:

: 61067-16-1
2,2-dimethyl-1,5-diphenyl-pentan-1-one

: 54007-91-9
(3,3-dimethylcyclopent-1-ene-1,2-diyl)dibenzene

Guidance literature:: Multi-step reaction with 2 steps

1: H₂S, HCl / ethanol / -78 °C

2: (i) (irradiation), benzene, (ii) Hg(OAc)2, AcOH

With hydrogenchloride; hydrogen sulfide; In ethanol;
DOI:10.1021/ja00436a025