Diazene, bis(2-iodophenyl)-

Base Information

• Chemical Name: Diazene, bis(2-iodophenyl)-
• CAS No.: 5486-04-4
• Molecular Formula: C12H8I2N2
• Molecular Weight: 434.018
• Hs Code.: 2927000090
• DSSTox Substance ID: DTXSID90403708
• Nikkaji Number: J3.340.363A
• Mol file: 5486-04-4.mol

Synonyms:5486-04-4;1,2-bis(2-iodophenyl)diazene;(E)-1,2-bis(2-iodophenyl)diazene;318514-96-4;Diazene, bis(2-iodophenyl)-;2,2'-Diiodoazobenzene;(E)-bis(2-iodophenyl)diazene;DTXSID90403708

Chemical Property of Diazene, bis(2-iodophenyl)-

Chemical Property:

• PSA: 24.72000
• LogP: 5.31120
• XLogP3: 5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 433.87769
• Heavy Atom Count: 16
• Complexity: 221

Purity/Quality:

95% ^*data from raw suppliers

Bis-(2-iodo-phenyl)-diazene 95% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C(=C1)N=NC2=CC=CC=C2I)I

Technology Process of Diazene, bis(2-iodophenyl)-

There total 13 articles about Diazene, bis(2-iodophenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

trans-azobenzene (17082-12-1) → (E)-1,2-bis(2-iodophenyl)diazene (5486-04-4)

Guidance literature:

With silver tetrafluoroborate; 1-iodo-butane; dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; [bis(acetoxy)iodo]benzene; In 1,2-dichloro-ethane; at 60 ℃; for 2h; Reagent/catalyst; regioselective reaction; Schlenk technique; Inert atmosphere;

DOI:10.1039/c8ob00318a

Reference yield: 82.0%

2-iodophenylamine (615-43-0) → 2,2′-diiodoazobenzene (5486-04-4)

Guidance literature:

With manganese(IV) oxide; In toluene; at 120 ℃; for 3h;

DOI:10.3390/molecules24020303

Reference yield: 67.0%

o-nitroiodobenzene (609-73-4) → (E)-1,2-bis(2-iodophenyl)diazene (5486-04-4)

Guidance literature:

In aq. phosphate buffer; water; acetonitrile; at 25 ℃; pH=3; Electrochemical reaction;

DOI:10.1021/acs.orglett.1c02304

upstream raw materials:

2-iodo benzoyl azide

2-iodophenylamine

o-iodophenylacetyl chloride

o-iodophenylacetic acid

Downstream raw materials:

2,2'-bis[bis(pentafluorophenyl)boryl]azobenzene