Methyl [diazo(phenyl)methyl]phenylphosphinate

Base Information

Chemical Name:Methyl [diazo(phenyl)methyl]phenylphosphinate
CAS No.:56641-52-2
Molecular Formula:C₁₄H₁₃N₂O₂P
Molecular Weight:272.243
Hs Code.:
DSSTox Substance ID:DTXSID00504058

Synonyms:56641-52-2;Methyl [diazo(phenyl)methyl]phenylphosphinate;DTXSID00504058

Suppliers and Price of Methyl [diazo(phenyl)methyl]phenylphosphinate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Methyl [diazo(phenyl)methyl]phenylphosphinate

Chemical Property:

XLogP3:2.8
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:4
Exact Mass:272.07146466
Heavy Atom Count:19
Complexity:392

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COP(=O)(C1=CC=CC=C1)C(=[N+]=[N-])C2=CC=CC=C2

Technology Process of Methyl [diazo(phenyl)methyl]phenylphosphinate

There total 1 articles about Methyl [diazo(phenyl)methyl]phenylphosphinate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 56641-52-2
α-Diazobenzyl(phenyl)phosphinsaeure-methylester

Guidance literature:: entspr. Tosylhydrazon;

Reference yield: 9.0%

: 56641-52-2
α-Diazobenzyl(phenyl)phosphinsaeure-methylester

: 513-81-5
2,3-dimethyl-buta-1,3-diene

: 75153-49-0,75196-87-1,75196-88-2,75196-89-3
(+/-)-(PS*,1S*,2S*)-2-Isopropenyl-2-methyl-1-phenylcyclopropyl(phenyl)phosphinsaeure-methylester

: (+/-)-(PR*,1S*,2S*)-2-Isopropenyl-2-methyl-1-phenylcyclopropyl(phenyl)phosphinsaeure-methylester

: (S)-((1R,2S)-2-Isopropenyl-2-methyl-1-phenyl-cyclopropyl)-phenyl-phosphinic acid methyl ester

: (+/-)-(PR*,1S*,2R*)-2-Isopropenyl-2-methyl-1-phenylcyclopropyl(phenyl)phosphinsaeure-methylester

Guidance literature:: for 4.5h; Yields of byproduct given; Irradiation;

Reference yield:

: 56641-52-2
α-Diazobenzyl(phenyl)phosphinsaeure-methylester

: 24091-69-8
(α-hydroxybenzyl)(phenyl)phosphinic acid

Guidance literature:: Multi-step reaction with 2 steps

1: benzene / Ambient temperature

2: 40 percent / H₂O / acetone

With water; In acetone; benzene;
DOI:10.1016/S0040-4020(01)96462-2