Benzene, 1-bromo-3-(trifluoroethenyl)-

Base Information

Chemical Name:Benzene, 1-bromo-3-(trifluoroethenyl)-
CAS No.:58174-57-5
Molecular Formula:C8H4BrF3
Molecular Weight:237.019
Hs Code.:
DSSTox Substance ID:DTXSID60481735
Nikkaji Number:J495.159J

Synonyms:Benzene, 1-bromo-3-(trifluoroethenyl)-;58174-57-5;DTXSID60481735

Suppliers and Price of Benzene, 1-bromo-3-(trifluoroethenyl)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Benzene, 1-bromo-3-(trifluoroethenyl)-

Chemical Property:

XLogP3:3.3
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:1
Exact Mass:235.94485
Heavy Atom Count:12
Complexity:187

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C1=CC(=CC(=C1)Br)C(=C(F)F)F

Technology Process of Benzene, 1-bromo-3-(trifluoroethenyl)-

There total 4 articles about Benzene, 1-bromo-3-(trifluoroethenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

: 1-(3-bromophenyl)-1,2,2,2-tetrafluoroethane

: 58174-57-5
m-bromo-1,2,2-trifluorostyrene

Guidance literature:: With lithium hexamethyldisilazane; In tetrahydrofuran; at 15 ℃; for 0.5h;
DOI:10.1016/S0040-4039(03)01628-9

Reference yield:

: 446-63-9,1188286-64-7
(±)-1-(3-bromophenyl)-2,2,2-trifluoroethanol

: 58174-57-5
m-bromo-1,2,2-trifluorostyrene

Guidance literature:: Multi-step reaction with 2 steps

1: 76 percent / diethylaminosulfur trifluoride / CH₂Cl₂ / -70 - 20 °C

2: 69 percent / LHMDS / tetrahydrofuran / 0.5 h / 20 °C

With diethylamino-sulfur trifluoride; lithium hexamethyldisilazane; In tetrahydrofuran; dichloromethane;
DOI:10.1016/j.jfluchem.2005.05.005

Reference yield:

: 447-14-3
1,2,2-trifluorostyrene

: 58174-57-5
m-bromo-1,2,2-trifluorostyrene

Guidance literature:: Multi-step reaction with 3 steps

1: Br₂

2: Br₂, Fe / hexane

3: Zn / diethyl ether; ethanol / Heating

With bromine; iron; zinc; In diethyl ether; ethanol; hexane;
DOI:10.1007/BF00921660