bis(4-fluorophenyl)peroxyanhydride

Base Information

• Chemical Name: bis(4-fluorophenyl)peroxyanhydride
• CAS No.: 582-92-3
• Molecular Formula: C14H8F2O4
• Molecular Weight: 278.212
• Mol file: 582-92-3.mol

Synonyms:

Chemical Property of bis(4-fluorophenyl)peroxyanhydride

Chemical Property:

• Vapor Pressure: 1.01E-05mmHg at 25°C

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of bis(4-fluorophenyl)peroxyanhydride

There total 4 articles about bis(4-fluorophenyl)peroxyanhydride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

4-Fluorobenzoic acid (456-22-4) → 4-fluorobenzoic peroxyanhydride (582-92-3)

Guidance literature:

With Eosin Y; triphenylphosphine; In N,N-dimethyl-formamide; at 20 ℃; Irradiation;

Reference yield: 85.0%

4-fluorobenzoyl chloride (403-43-0) → 4-fluorobenzoic peroxyanhydride (582-92-3)

Guidance literature:

With dihydrogen peroxide; In diethyl ether; water; for 0.166667h;

DOI:10.1021/ol900756g

Reference yield:

p-fluorotoluene (352-32-9) → 4-fluorobenzoic peroxyanhydride (582-92-3)

Guidance literature:

Multi-step reaction with 3 steps

1: aqueous sulfuric acid; lead (IV)-oxide-anodes

2: thionyl chloride

3: diethyl ether; barium peroxid octahydrate

With thionyl chloride; barium peroxide; diethyl ether; sulfuric acid;

DOI:10.1002/hlca.193301601142

upstream raw materials:

4-fluorobenzoyl chloride

p-fluorotoluene

4-Fluorobenzoic acid

Downstream raw materials:

4,4'''-difluoro-p-quaterphenyl

3-(4-fluorophenyl)-1-methylquinoxalin-2(1H)-one

2-(4-fluorophenyl)-5-phenyl-2H-tetrazole

fluorobenzene

Refernces

• 1、 Botla, Vinayak,Pilli, Navyasree,Malapaka, Chandrasekharam. "Uncatalyzed, on water oxygenative cleavage of inert C-N bond with concomitant 8,7-amino shift in 8-aminoquinoline derivatives". supporting information. p. 1735 - 1742. Retrieved 2019/04/08.
• 2、 Vinayak, Botla,Navyasree, Pilli,Chandrasekharam, Malapaka. "Iron(iii)-catalyzed chelation assisted remote C-H bond oxygenation of 8-amidoquinolines". . p. 9200 - 9208. Retrieved 2017/11/14.