1H-1,2,3-triazol-1-amine

Base Information

• Chemical Name: 1H-1,2,3-triazol-1-amine
• CAS No.: 584-14-5
• Molecular Formula: C2H4N4
• Molecular Weight: 84.0806
• Hs Code.: 2933990014
• DSSTox Substance ID: DTXSID40396939
• Nikkaji Number: J324.891G
• Wikidata: Q82197915
• Mol file: 584-14-5.mol

Synonyms:1H-1,2,3-triazol-1-amine;584-14-5;triazol-1-amine;Triazol-3-amine;MFCD01874348;n-aminotriazole;Trapidil impurity B;1,2,3-triazolium-1-aminide;1-amino-1h-1,2,3-triazole;DTXSID40396939;MPSUGQWRVNRJEE-UHFFFAOYSA-N;STK379215;AKOS005450602;AB92480;AM806566;CS-0044749;D72001;EN300-245863

Chemical Property of 1H-1,2,3-triazol-1-amine

Chemical Property:

• Melting Point: 49-50 °C
• Boiling Point: 244.9±23.0 °C(Predicted)
• PKA: -0.19±0.70(Predicted)
• PSA: 56.73000
• Density: 1.59±0.1 g/cm3(Predicted)
• LogP: -0.42690
• Storage Temp.: Keep in dark place,Inert atmosphere,Room temperature
• XLogP3: -0.6
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 84.043596145
• Heavy Atom Count: 6
• Complexity: 44.8

Purity/Quality:

95% ^*data from raw suppliers

1H-1,2,3-Triazol-1-amine 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C1=CN(N=N1)N

Technology Process of 1H-1,2,3-triazol-1-amine

There total 11 articles about 1H-1,2,3-triazol-1-amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

glyoxal bis(hydrazone) (3327-62-6) → 1-amino-1,2,3-triazole (584-14-5)

Guidance literature:

With manganese dioxide; In ethanol;

Reference yield: 88.0%

glyoxal bishydrazone (7677-13-6) → 1-amino-1,2,3-triazole (584-14-5)

Guidance literature:

With manganese(IV) oxide; In acetonitrile; at 20 ℃; for 1h;

DOI:10.1002/jhet.5570420104

Reference yield: 85.5%

glyoxime (557-30-2) → 1-amino-1,2,3-triazole (584-14-5)

Guidance literature:

With ammonium sulfate; dihydrogen peroxide; In water; acetonitrile; at 25 - 35 ℃; for 3h; Reagent/catalyst;

upstream raw materials:

1 ,2,3-Triazole

N′-(2,2-dichloroethylidene)-4-methylbenzenesulfonohydrazide

N-methanesulfonic 2,2-dichloroethylidene Hydrazide

glyoxal bishydrazone

Downstream raw materials:

1-amino-1,2,3-triazolium nitrate

5-[2-benzoylimino-3-(4-methoxyphenyl)-1,3,4-thiadiazol-5-yl]-[1,2,4]triazolo[1,5-a]pyrimidine

5-[2-benzoylimino-3-(4-chlorophenyl)-1,3,4-thiadiazol-5-yl]-[1,2,4]triazolo[1,5-a]pyrimidine

5-(2-benzoylimino-3-(4-nitrophenyl)-1,3,4-thiadiazol-5-yl)-[1,2,4]triazolo[1,5-a]pyrimidine

Refernces

• 1、 Zhao, Xiao-Hui,Ye, Zhi-Wen. "A facile synthesis of a novel energetic surfactant 1-amino-3-dodecyl-1,2,3- triazolium nitrate". . p. 209 - 211. Retrieved 2014.
• 2、 -. "Method for continuously synthesizing 1H-1,2,3-triazole by using microchannel reactor". Paragraph 0020; 0046; 0048; 0052; 0054; 0058; 0060. . Retrieved 2021/05/19.
• 3、 -. "Preparation method of 1-amino-1,2,3-triazole". Paragraph 0034-0046. . Retrieved 2021/04/10.