Benzenamine, 3,5-dichloro-4-[6-methoxy-5-(1-methylethenyl)-1-naphthalenyl]-

Base Information

Chemical Name:Benzenamine, 3,5-dichloro-4-[6-methoxy-5-(1-methylethenyl)-1-naphthalenyl]-
CAS No.:588718-04-1
Molecular Formula:C20H17Cl2NO
Molecular Weight:358.267
Hs Code.:

Synonyms:

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Chemical Property of Benzenamine, 3,5-dichloro-4-[6-methoxy-5-(1-methylethenyl)-1-naphthalenyl]-

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Technology Process of Benzenamine, 3,5-dichloro-4-[6-methoxy-5-(1-methylethenyl)-1-naphthalenyl]-

There total 8 articles about Benzenamine, 3,5-dichloro-4-[6-methoxy-5-(1-methylethenyl)-1-naphthalenyl]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 588718-03-0
5-(2,6-dichloro-4-nitro-phenyl)-1-isopropenyl-2-methoxy-naphthalene

: 588718-04-1
3,5-dichloro-4-(5-isopropenyl-6-methoxy-naphthalen-1-yl)-phenylamine

Guidance literature:: With iron; acetic acid; at 20 ℃; for 16h;
DOI:10.1016/j.bmcl.2005.06.093

Reference yield:

: 22604-07-5
6-methoxy-1-naphthol

: 588718-04-1
3,5-dichloro-4-(5-isopropenyl-6-methoxy-naphthalen-1-yl)-phenylamine

Guidance literature:: Multi-step reaction with 6 steps

1: 99 percent / Et₃N / CH₂Cl₂ / -40 - -10 °C

2: 58 percent / potassium acetate / PdCl₂(dppf) / 4 h / 80 °C

3: 69 percent / aq. Na₂CO₃; Pd(PPh₃)4 / 1,2-dimethoxy-ethane / 0.5 h / 80 °C

4: 77 percent / (CH₃)2SBF₃ / CH₂Cl₂ / 16 h / 20 °C

5: 27 percent / TiCl₄ / CH₂Cl₂; tetrahydrofuran / 16 h / 20 °C

6: 99 percent / aq. acetic acid; iron / 16 h / 20 °C

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; boron dimethyl-trifluoro sulphide; potassium acetate; titanium tetrachloride; iron; sodium carbonate; acetic acid; triethylamine; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; In tetrahydrofuran; 1,2-dimethoxyethane; dichloromethane; 3: Suzuki coupling;
DOI:10.1016/j.bmcl.2005.06.093

Reference yield:

: 350584-53-1
6-(methyloxy)-1-naphthalenyl trifluoromethanesulfonate

: 588718-04-1
3,5-dichloro-4-(5-isopropenyl-6-methoxy-naphthalen-1-yl)-phenylamine

Guidance literature:: Multi-step reaction with 5 steps

1: 58 percent / potassium acetate / PdCl₂(dppf) / 4 h / 80 °C

2: 69 percent / aq. Na₂CO₃; Pd(PPh₃)4 / 1,2-dimethoxy-ethane / 0.5 h / 80 °C

3: 77 percent / (CH₃)2SBF₃ / CH₂Cl₂ / 16 h / 20 °C

4: 27 percent / TiCl₄ / CH₂Cl₂; tetrahydrofuran / 16 h / 20 °C

5: 99 percent / aq. acetic acid; iron / 16 h / 20 °C

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; boron dimethyl-trifluoro sulphide; potassium acetate; titanium tetrachloride; iron; sodium carbonate; acetic acid; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; In tetrahydrofuran; 1,2-dimethoxyethane; dichloromethane; 2: Suzuki coupling;
DOI:10.1016/j.bmcl.2005.06.093