Cyclohexanone, 4-(1,1-dimethylethyl)-, dimethylhydrazone

Base Information

• Chemical Name: Cyclohexanone, 4-(1,1-dimethylethyl)-, dimethylhydrazone
• CAS No.: 58911-63-0
• Molecular Formula: C12H24N2
• Molecular Weight: 196.336
• Mol file: 58911-63-0.mol

Synonyms:

Chemical Property of Cyclohexanone, 4-(1,1-dimethylethyl)-, dimethylhydrazone

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Cyclohexanone, 4-(1,1-dimethylethyl)-, dimethylhydrazone

There total 1 articles about Cyclohexanone, 4-(1,1-dimethylethyl)-, dimethylhydrazone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

4-tercbutyl-cyclohexanone (98-53-3) + N,N-Dimethylhydrazine (57-14-7) → 4-tert-butylcyclohexanone dimethylhydrazone (58911-63-0)

Guidance literature:

In ethanol; toluene; for 24h; Heating;

DOI:10.1021/ja00255a005

Reference yield: 88.0%

4-tert-butylcyclohexanone dimethylhydrazone (58911-63-0) → 4-tercbutyl-cyclohexanone (98-53-3)

Guidance literature:

With K5; In acetonitrile; at 20 ℃; for 1.5h;

DOI:10.1055/s-2003-40998

Reference yield: 60.0%

4-tert-butylcyclohexanone dimethylhydrazone (58911-63-0) → 1,1-difluoro-4-t-butylcyclohexane (19422-34-5) + 3-Iodo-4,4-difluoro-1-tert-butylcyclohexane (133932-42-0)

Guidance literature:

With iodine monofluoride; In chloroform; for 1h; Ambient temperature;

DOI:10.1021/jo00015a024

upstream raw materials:

4-tercbutyl-cyclohexanone

N,N-Dimethylhydrazine

Downstream raw materials:

[(1S,5R)-5-tert-Butyl-2-(dimethyl-hydrazono)-cyclohexyl]-methanol

[(1R,5R)-5-tert-Butyl-2-(dimethyl-hydrazono)-cyclohexyl]-methanol

(2S,4R)-2-((E)-2-Bromo-but-2-enyl)-4-tert-butyl-1-methylene-cyclohexane

1,1-difluoro-4-t-butylcyclohexane

Refernces

• 1、 Basso,Kaiser,Rittner,Lambert. "Axial/equatorial proportions for 2-substituted cyclohexanones". . p. 7865 - 7869. Retrieved 2007/10/02.