Bis[di-tert-butyl(phenyl)phosphoranylidene]platinum(IV)

Base Information

Chemical Name:Bis[di-tert-butyl(phenyl)phosphoranylidene]platinum(IV)
CAS No.:59765-06-9
Molecular Formula:C28H46P2Pt
Molecular Weight:639.69000
Hs Code.:
Mol file:59765-06-9.mol

Synonyms:Platinum,bis[bis(1,1-dimethylethyl)phenylphosphine];bis(di-t-butylphenylphosphine)platinum(0);

Suppliers and Price of Bis[di-tert-butyl(phenyl)phosphoranylidene]platinum(IV)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of Bis[di-tert-butyl(phenyl)phosphoranylidene]platinum(IV)

Chemical Property:

PSA：27.18000
LogP:8.77910

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Bis[di-tert-butyl(phenyl)phosphoranylidene]platinum(IV)

There total 2 articles about Bis[di-tert-butyl(phenyl)phosphoranylidene]platinum(IV) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 85931-08-4
{PtH(NH₃)(P(C(CH₃)3)2(C₆H₅))2}⁽¹⁺⁾*PF₆^(1-)={PtH(NH₃)(P(C(CH₃)3)2(C₆H₅))2}PF₆

: 59765-06-9
bis(di-t-butylphenylphosphine)platinum⁽⁰⁾

Guidance literature:: With ammonia; In acetone; under Ar; bubbling of NH3 through an acetone solution of teh Pt complex at 25°C; filtration, washing with acetone, drying, NMR anal.;
DOI:10.1016/S0022-328X(00)98622-4

Reference yield: 34.0%

: [Pt(allyl)Cl]4

: 32673-25-9
di(tertbutyl)phenylphosphine

: 59765-06-9
bis(di-t-butylphenylphosphine)platinum⁽⁰⁾

Guidance literature:: With potassium tert-butylate; In tetrahydrofuran; 60°C, overnight, under N2; THF evapd. in vac., the residue extd. with toluene, filtered, the soln.evapd. in vac., the residue pumped in vac. at 65°C, the residue dissolved in heptane and filtered, pptn. by cooling to -20°C, thecrystals dried in vac.; elem. anal.;
DOI:10.1039/DT9800000776

Reference yield: 90.0%

: ammonium hexafluorophosphate

: 59765-06-9
bis(di-t-butylphenylphosphine)platinum⁽⁰⁾

: 85931-08-4
{PtH(NH₃)(P(C(CH₃)3)2(C₆H₅))2}⁽¹⁺⁾*PF₆^(1-)={PtH(NH₃)(P(C(CH₃)3)2(C₆H₅))2}PF₆

Guidance literature:: In tetrahydrofuran; stirring of starting compounds in THF under Ar at 25°C for 48 h; all operations under Ar: evapn., addn. of CH2Cl2, filtration (florisil), addn. of pentane, cooling, elem. anal.;
DOI:10.1016/S0022-328X(00)98622-4