85931-08-4Relevant academic research and scientific papers
PROTONATION OF TERTIARY PHOSPHINE PLATINUM(0) COMPLEXES BY AMMONIUM ION. CHARACTERIZATION AND SOME REACTIONS OF THE RESULTING HYDRIDES
Goel, Ram G.,Srivastava, Ramesh C.
, p. 303 - 310 (2007/10/02)
The platinum(0) complexes Pt(PR3)2 (R3=(t-Bu)3 and (t-Bu)2Ph) react readily with the ammonium salts NH4X (X=PF6 and ClO4) to give the cationic ammine hydrides trans-X.Reaction of Pt(PPH3)3 with NH4PF6 affords PF6.The ammine hyd
